Open‐framework inorganic materials

AK Cheetham, G Férey… - Angewandte Chemie …, 1999 - Wiley Online Library
Aluminosilicate zeolites such as UTD‐1 (structure shown) belong to a family of nanoporous
inorganic materials that find utility in catalysis, separation, and ion exchange. During the last …

Solventothermal synthesis of solid‐state chalcogenidometalates

WS Sheldrick, M Wachhold - … Chemie International Edition in …, 1997 - Wiley Online Library
Abstract Development of solventothermal methods in the intermediate‐temperature (100–
600° C) range has been motivated by current interest in the design of solid‐state …

Supertetrahedral sulfide crystals with giant cavities and channels

H Li, A Laine, M O'keeffe, OM Yaghi - Science, 1999 - science.org
Although aluminosilicates and metal phosphates can form porous open-framework materials
such as zeolites, sulfide analogs usually form high-density phases because of the relatively …

Chalcogenidometalates of the heavier Group 14 and 15 elements

WS Sheldrick, M Wachhold - Coordination chemistry reviews, 1998 - Elsevier
The review covers structural aspects of the chemistry of ternary and quaternary
chalcogenidometalates of the heavier Group 14 (Ge, Sn, Pb) and 15 (As, Sb, Bi) elements …

Low temperature route towards new materials: solvothermal synthesis of metal chalcogenides in ethylenediamine

J Li, Z Chen, RJ Wang, DM Proserpio - Coordination Chemistry Reviews, 1999 - Elsevier
Solid state reactions occur among solid reactants and are characterized by slow nucleation
and diffusion processes. Thus, high temperature is often required to promote the reactions to …

Anorganische Materialien mit offenen Gerüsten

AK Cheetham, G Férey, T Loiseau - Angewandte Chemie, 1999 - Wiley Online Library
Die alumosilicatischen Zeolithe wie UTD‐1 (siehe Bild) bilden eine bemerkenswerte Familie
nanoporöser anorganischer Materialien, die in der Katalyse, in Trennverfahren und als …

Solvothermal crystal growth of CuSbQ2 (Q= S, Se) and the correlation between macroscopic morphology and microscopic structure

J Zhou, GQ Bian, QY Zhu, Y Zhang, CY Li… - Journal of Solid State …, 2009 - Elsevier
A low temperature solvothermal method has been successfully used for preparation of two
semiconductor compounds CuSbQ2 (Q= S (1), Se (2)) by the reactions of Cu, Sb and S (or …

Three-dimensional open framework built from Cu− S icosahedral clusters and its photocatalytic property

Z Zhang, J Zhang, T Wu, X Bu… - Journal of the American …, 2008 - ACS Publications
Reported here is an extraordinary and unprecedented sulfide containing icosahedral
[Cu8S12] 16− clusters that behave like a pseudo-octahedral unit in the bonding pattern and …

[Co(en)3]CoSb4S8:  A Novel Non-Centrosymmetric Lamellar Heterometallic Sulfide with Large-Framework Holes

HO Stephan, MG Kanatzidis - Journal of the American Chemical …, 1996 - ACS Publications
Sulfide-based open-framework materials are intriguing compounds. Apart from the fact that
they possess a very diverse and therefore interesting structural chemistry, these materials …

Organically directed heterometallic chalcogenidometalates containing group 12 (II)/13 (III)/14 (IV) metal ions and antimony (III)

KY Wang, ML Feng, XY Huang, J Li - Coordination Chemistry Reviews, 2016 - Elsevier
Crystalline chalcogenidometalates are a class of solid-state materials with great significance
for both basic science and technological applications. The strong dependence of their …