Nanofluidics, from bulk to interfaces

L Bocquet, E Charlaix - Chemical Society Reviews, 2010 - pubs.rsc.org
Nanofluidics has emerged recently in the footsteps of microfluidics, following the quest for
scale reduction inherent to nanotechnologies. By definition, nanofluidics explores transport …

Reversed Hofmeister series—The rule rather than the exception

N Schwierz, D Horinek, U Sivan, RR Netz - Current opinion in colloid & …, 2016 - Elsevier
Over recent years, the supposedly universal Hofmeister series has been replaced by a
diverse spectrum of direct, partially altered and reversed series. This review aims to provide …

Modulating the zeta potential of cellulose nanocrystals using salts and surfactants

R Prathapan, R Thapa, G Garnier, RF Tabor - Colloids and Surfaces A …, 2016 - Elsevier
The zeta potential of cellulose nanocrystal (CNC) aqueous dispersions was studied as a
function of solution conditions, including changing pH and different electrolyte identities and …

Anionic and cationic Hofmeister effects on hydrophobic and hydrophilic surfaces

N Schwierz, D Horinek, RR Netz - Langmuir, 2013 - ACS Publications
Using a two-step modeling approach, we address the full spectrum of direct, reversed, and
altered ionic sequences as the charge of the ion, the charge of the surface, and the surface …

Reversed anionic Hofmeister series: the interplay of surface charge and surface polarity

N Schwierz, D Horinek, RR Netz - Langmuir, 2010 - ACS Publications
We describe a two-scale modeling approach toward anion specificity at surfaces of varying
charge and polarity. Explicit-solvent atomistic molecular dynamics simulations at neutral …

Profile of the static permittivity tensor of water at interfaces: Consequences for capacitance, hydration interaction and ion adsorption

DJ Bonthuis, S Gekle, RR Netz - Langmuir, 2012 - ACS Publications
We derive the theoretical framework to calculate the dielectric response tensor and
determine its components for water adjacent to hydrophilic and hydrophobic surfaces using …

Elucidating the mechanism of selective ion adsorption to the liquid water surface

DE Otten, PR Shaffer, PL Geissler… - Proceedings of the …, 2012 - National Acad Sciences
Adsorption of aqueous thiocyanate ions from bulk solution to the liquid/vapor interface was
measured as a function of temperature by resonant UV second harmonic generation …

Surface tensions, surface potentials, and the Hofmeister series of electrolyte solutions

AP dos Santos, A Diehl, Y Levin - Langmuir, 2010 - ACS Publications
A theory is presented which allows us to accurately calculate the surface tensions and the
surface potentials of electrolyte solutions. Both the ionic hydration and the polarizability are …

Image-charge effects on ion adsorption near aqueous interfaces

CY Son, ZG Wang - … of the National Academy of Sciences, 2021 - National Acad Sciences
Electrostatic interactions near surfaces and interfaces are ubiquitous in many fields of
science. Continuum electrostatics predicts that ions will be attracted to conducting …

Simulation and theory of ions at atmospherically relevant aqueous liquid-air interfaces

DJ Tobias, AC Stern, MD Baer, Y Levin… - Annual review of …, 2013 - annualreviews.org
Chemistry occurring at or near the surface of aqueous droplets and thin films in the
atmosphere influences air quality and climate. Molecular dynamics simulations are …