Spontaneous Reduction by One Electron on Water Microdroplets Facilitates Direct Carboxylation with CO2

H Chen, R Wang, J Xu, X Yuan, D Zhang… - Journal of the …, 2023 - ACS Publications
Recent advances in microdroplet chemistry have shown that chemical reactions in water
microdroplets can be accelerated by several orders of magnitude compared to the same …

The metallo-formate anions, M (CO 2)−, M= Ni, Pd, Pt, formed by electron-induced CO 2 activation

G Liu, SM Ciborowski, Z Zhu, Y Chen… - Physical Chemistry …, 2019 - pubs.rsc.org
The metallo-formate anions, M (CO2)−, M= Ni, Pd, and Pt, were formed by electron-induced
CO2 activation. They were generated by laser vaporization and characterized by a …

Electron Attachment to the (O2···CO2) van der Waals Complex Results in a Monomeric Anion (O2–CO2), a Possible Form of CO4

SH Lee, N Kim, TR Kim, S Shin… - The Journal of Physical …, 2021 - ACS Publications
We found that electron attachment to the van der Waals complex (O2··· CO2) turns the weak
intermolecular bond into a pseudochemical bond of significant strength. The resulting …

Vibrational Characterization of Radical Ion Adducts between Imidazole and CO2

SM Craig, CJ Johnson, DS Ranasinghe… - The Journal of …, 2018 - ACS Publications
We address the molecular level origins of the dramatic difference in the catalytic
mechanisms of CO2 activation by the seemingly similar molecules pyridine (Py) and …

Vibrational Characterization of Radical Ion Adducts Between Imidazole and C 02

CJ Johnson, DS Ranasinghe, A Perera, RJ Bartlett - search.proquest.com
The reduction chemistry of CO2 is currently under intensive investigation, largely because of
its importance in CO? capture and chemical transformation into liquid fuels.'0 Here we are …