Transition-metal mediated carbon–sulfur bond activation and transformations: an update

J Lou, Q Wang, P Wu, H Wang, YG Zhou… - Chemical Society …, 2020 - pubs.rsc.org
Carbon–sulfur bond cross-coupling has become more and more attractive as an alternative
protocol to establish carbon–carbon and carbon–heteroatom bonds. Diverse …

Electro-organic synthesis: an environmentally benign alternative for heterocycle synthesis

S Devi, D Wadhwa, J Sindhu - Organic & biomolecular chemistry, 2022 - pubs.rsc.org
Heterocyclic compounds are considered to be one of the most established structural classes
due to their extensive application in agrochemicals, pharmaceuticals and organic materials …

Metal‐Free Electrochemical Synthesis of Sulfonamides Directly from (Hetero)arenes, SO2, and Amines

SP Blum, T Karakaya, D Schollmeyer… - Angewandte Chemie …, 2021 - Wiley Online Library
Sulfonamides are among the most important chemical motifs in pharmaceuticals and
agrochemicals. However, there is no methodology to directly introduce the sulfonamide …

Electrochemical Synthesis of Thienoacene Derivatives: Transition‐Metal‐Free Dehydrogenative C− S Coupling Promoted by a Halogen Mediator

K Mitsudo, R Matsuo, T Yonezawa… - Angewandte Chemie …, 2020 - Wiley Online Library
The first electrochemical dehydrogenative C− S bond formation leading to thienoacene
derivatives is described. Several thienoacene derivatives were synthesized by …

The electrochemically selective C3-thiolation of quinolines

D Wang, L Zhang, F Xiao, G Mao… - Organic Chemistry …, 2022 - pubs.rsc.org
An electrochemical method has been developed to achieve the C3-thiolation of quinoline
compounds. Achievements of this new strategy included maximum atom economy, direct …

Recent Trends in Nickel‐Catalyzed C− S Bond Formation

US Kanchana, EJ Diana… - Asian Journal of Organic …, 2022 - Wiley Online Library
Recently, sulphur containing molecules have witnessed significant recognition due to their
wide application in various fields. In this regard, the synthesis of such C− S containing …

Silver-Catalyzed (Z)-β-Fluoro-vinyl Iodonium Salts from Alkynes: Efficient and Selective Syntheses of Z-Monofluoroalkenes

AT Sedikides, AJJ Lennox - Journal of the American Chemical …, 2024 - ACS Publications
Monofluoroalkenes are stable and lipophilic amide bioisosteres used in medicinal
chemistry. However, efficient and stereoselective methods for synthesizing Z …

Isothiouronium-Mediated Conversion of Carboxylic Acids to Cyanomethyl Thioesters

I Tiefenbrunner, BR Brutiu, T Stopka… - The Journal of Organic …, 2023 - ACS Publications
We report the development of an isothiouronium salt as a reagent for the operationally
simple synthesis of cyanomethyl thioesters with high functional group tolerance and …

Supported Cu (II)-Schiff base: novel heterogeneous catalyst with extremely high activity for eco-friendly, one-pot and multi-component C–S bond-forming reaction …

P Shiri, AM Amani, J Aboonajmi - Molecular Diversity, 2022 - Springer
An effective and proficient process for the synthesis of a variety of thioethers via the one‐
step reaction of benzyl halides, aryl halides, and thiourea is presented. This strategy is a one …

Preparation of Sulfonyl Chlorides by Oxidative Chlorination of Thiols and Disulfides using HNO3/HCl/O2 in a Flow Reactor

N Sulzer, D Polterauer, CA Hone, CO Kappe - ChemSusChem, 2024 - Wiley Online Library
A continuous flow metal‐free protocol for the synthesis of sulfonyl chlorides from thiols and
disulfides in the presence of nitric acid, hydrochloric acid and oxygen was developed. The …