To each his own: isonitriles for all flavors. Functionalized isocyanides as valuable tools in organic synthesis
M Giustiniano, A Basso, V Mercalli… - Chemical Society …, 2017 - pubs.rsc.org
The term functionalized isocyanides refers to all those isocyanides in which a neighbouring
functional group can finely tune the reactivity of the isocyano group or can be exploited in …
functional group can finely tune the reactivity of the isocyano group or can be exploited in …
One Reacts as Two: Applications of N-Isocyaniminotriphenylphosphorane in Diversity-Oriented Synthesis
GM Ojeda-Carralero, LG Ceballos, J Coro… - ACS Combinatorial …, 2020 - ACS Publications
N-Isocyaniminotriphenylphosphorane (NIITP) is a functionalized isonitrile that has been
extensively applied in a variety of organic reactions during the last two decades. This …
extensively applied in a variety of organic reactions during the last two decades. This …
Silver-Mediated [3 + 2] Cycloaddition of Alkynes and N-Isocyanoiminotriphenylphosphorane: Access to Monosubstituted Pyrazoles
F Yi, W Zhao, Z Wang, X Bi - Organic letters, 2019 - ACS Publications
A silver-mediated [3+ 2] cycloaddition of “CNN” and “C≡ C” for constructing pyrazoles has
been described. The “CNN” building block used is N-isocyanoiminotriphenylphosphorane …
been described. The “CNN” building block used is N-isocyanoiminotriphenylphosphorane …
Synthesis, carbonic anhydrase inhibition, anticancer activity, and molecular docking studies of 1, 3, 4-oxadiazole derivatives
In this work, we have synthesized various organic compounds possessing 1, 3, 4-oxadiazole
as a core structure and the structure of the newly synthesized target compounds has been …
as a core structure and the structure of the newly synthesized target compounds has been …
Silver-Mediated Direct C–H Cyanation of Terminal Alkynes with N-Isocyanoiminotriphenylphosphorane
H Wang, P Mi, W Zhao, R Kumar, X Bi - Organic letters, 2017 - ACS Publications
A direct cyanation of terminal alkynes for the synthesis of propionitrile derivatives, with the
aid of silver salt using water additive, has been achieved. The cyano source used is N …
aid of silver salt using water additive, has been achieved. The cyano source used is N …
[HTML][HTML] Preparation of fully substituted 1, 3, 4-oxadiazole derivatives from N-isocyaniminotriphenylphosphorane,(E)-cinnamic acids, chloroacetone and primary …
A Ramazani, FZ Nasrabadi, Z Karimi… - Bulletin of the Korean …, 2011 - koreascience.kr
The 1: 1 imine intermediate generated by the addition of primary amine to chloroacetone is
trapped by N-isocyaniminotriphenylphosphorane in the presence of (E)-cinnamic acids and …
trapped by N-isocyaniminotriphenylphosphorane in the presence of (E)-cinnamic acids and …
Synthesis of 1,3,4-oxadiazoles from the reaction of N-isocyaniminotriphenylphosphorane (NICITPP) with cyclohexanone, a primary amine and an aromatic carboxylic acid via …
The 1: 1 imine intermediate generated by the addition of a primary amine to cyclohexanone
trapped by N-isocyaniminotriphenylphosphorane (NICITPP) in the presence of aromatic …
trapped by N-isocyaniminotriphenylphosphorane (NICITPP) in the presence of aromatic …
Syntheses and medicinal chemistry of azepinoindolones: a look back to leap forward
M Kadagathur, S Patra, DK Sigalapalli… - Organic & …, 2021 - pubs.rsc.org
Nitrogen-containing heterocyclic scaffolds constitute nearly 75% of small molecules which
favorably act as drug candidates. For the past few decades, numerous natural and synthetic …
favorably act as drug candidates. For the past few decades, numerous natural and synthetic …
Reactivity of N-(isocyanoimino) triphenylphosphorane toward group 13 Lewis acids
B Tang, S Ju, W Yan, T Chen, DW Stephan… - Chemical …, 2024 - pubs.rsc.org
The species Ph3PNNC 1 reacts with the group 13 Lewis acids E (C6F5) 3 (E= B or Al), HB
(C6F5) 2, ClAl (C6F5) 2 and ECl3 (E= Ga or In) to give the Lewis acid–base adduct …
(C6F5) 2, ClAl (C6F5) 2 and ECl3 (E= Ga or In) to give the Lewis acid–base adduct …
Efficient synthesis of quinolines via a Knoevenagel/Staudinger/aza-Wittig sequence
F Qu, P He, RF Hu, XH Cheng, S Wang… - Synthetic …, 2015 - Taylor & Francis
A simple and efficient method for the construction of quinoline derivatives from 2-
azidobenzaldehyde and various carbonyl compounds was developed. The process involves …
azidobenzaldehyde and various carbonyl compounds was developed. The process involves …