Chemical systems consist of chemical elements and chemical bonds. Strong, covalent
bonds are expected between open-shell species, when more bonding molecular orbitals …

Aluminosilicate zeolites such as UTD‐1 (structure shown) belong to a family of nanoporous
inorganic materials that find utility in catalysis, separation, and ion exchange. During the last …

Abstract Development of solventothermal methods in the intermediate‐temperature (100–
600° C) range has been motivated by current interest in the design of solid‐state …

Crystalline semiconducting sulfide and selenide zeolite analogs were synthesized that
possess four-connected, three-dimensional tetrahedral networks built from tetravalent (M4+ …

The review covers structural aspects of the chemistry of ternary and quaternary
chalcogenidometalates of the heavier Group 14 (Ge, Sn, Pb) and 15 (As, Sb, Bi) elements …

The efficient capture of radionuclides with long half-lives such as technetium-99 (99Tc),
uranium-238 (238U), and iodine-129 (129I) is pivotal to prevent their transport into …

Metal chalcogenide supertetrahedral clusters (MCSCs) are of significance for developing
crystalline porous framework materials and atomically precise cluster chemistry. Early …

The synthesis and exploration of heterobimetallic chalcogenide compounds has been
studied intensely during the last decade. Besides the general interest in the exploration of …

Crystalline chalcogenides belong to the most promising class of materials. In addition to
dense solid‐state structures, they may form molecular cluster arrangements and networks …

A method for expanding the pores in crystalline frameworks is demonstrated with the
substitution of face-capped octahedral [Re6Q8 (CN) 6] 4-(Q= Se, Te) clusters into the …