Electrochemical dearomative spirocyclization

N Li, Z Shi, WZ Wang, Y Yuan… - Chemistry–An Asian …, 2023 - Wiley Online Library
Electrochemical dearomative spirocyclization serves as a green and sustainable approach
to convert the flat, two‐dimension aromatic feedstock into the value‐added three‐dimension …

Electrochemical cascade reactions: an account of recent developments for this modern strategic tool in the arsenal of chemical synthesis

MK Yadav, S Chowdhury - Green Chemistry, 2023 - pubs.rsc.org
In view of the growing demand for synthetic molecules or materials by researchers from both
the core sciences and interdisciplinary sectors, the field of organic synthesis needs to be …

Cp2Fe Mediated Electrochemical Synthesis of Phosphonylated Spirocyclic Indolines via Dearomatization of Indoles

K Mo, X Zhou, J Wang, J Wu, Y Zhao - Organic Letters, 2023 - ACS Publications
A general and robust strategy for the synthesis of phosphonylated spirocyclic indolines has
been developed through Cp2Fe-catalyzed electrochemical dearomaztizaion of indoles …

Electrochemical synthesis of vicinal azidoacetamides

Y Yu, Y Yuan, KY Ye - Chemical Communications, 2023 - pubs.rsc.org
Vicinal diamines are an important structural motif in bioactive natural products and
pharmaceutical intermediates. Herein, an environmentally friendly and efficient …

Recent Advances in The Electrochemical Functionalization of N-heterocycles

S Chowdhury, MK Yadav - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
Nitrogen-containing heterocyclic cores are of immense importance due to their high
abundance in naturally occurring or synthetic molecules having wide applications in …

Diradical Polar Reactivity Induced by Electricity‐Mediated Ground State Triplet Nitrenium Species

N Banerjee, A Kushwaha, S Dutt… - Advanced Synthesis …, 2024 - Wiley Online Library
It is extremely rare for reactive intermediates to possess a ground state triplet character.
Excited state triplet intermediates are generally accessed by means of photon transfer from a …

Metal-free nitro/azido cyclization of 1-acryloyl-2-cyanoindoles to access NO 2/N 3-featuring pyrrolo [1, 2-a] indolediones

H Liu, Q Yan, Y Zeng, X Hou, Y Wang, L Li… - Organic & Biomolecular …, 2024 - pubs.rsc.org
An H2O/heating or [bis (trifluoroacetoxy) iodo] benzene promoted radical cascade
nitro/azide cyclization of 1-acryloyl-2-cyanoindoles with tert-butyl nitrite/azidotrimethylsilane …

Recent Progress in Metal-Catalyzed C (sp³)-P Bond Formation

JL Tu, Z Shen, B Huang - Tetrahedron, 2024 - Elsevier
The construction of C (sp³)-P bonds is of paramount importance in organic synthesis,
catalysis, and materials science. Organophosphorus compounds containing C (sp³)-P bonds …

Copper(II)‐Catalyzed Cascade Reactions of N‐Aryl Nitrones and Disubstituted Allenoates to Prepare [1,3]Oxazino[3,2‐a]indolines and Dihydropyrido[1,2‐a]indolines

PP Xu, SG Xin, X Li, C Liang… - Advanced Synthesis & …, 2023 - Wiley Online Library
We described a copper (II)‐catalyzed [3+ 2] cycloaddition of N‐aryl‐α, β‐unsaturated
nitrones with disubstituted allenoates bifurcated to prepare various [1, 3] oxazino [3, 2‐a] …

Modern electrosynthesis of spiro compounds

MN Elinson, YE Ryzhkova, FV Ryzhkov… - Russian Chemical …, 2024 - Springer
Spirocyclic scaffolds have received increasing interest because of their wide use in
medicinal chemistry and the need for designing new effective drugs on their basis …