[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

Single-ion magnetism behaviors in lanthanide (III) based coordination frameworks

Q Wan, M Wakizaka, M Yamashita - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
Single-ion magnets (SIMs) and single-molecule magnets (SMMs) are typically made up of
3d and/or 4f complexes that possess significant energy barriers to prevent the spin reversal …

Multifunctional lanthanide-based single-molecule magnets exhibiting luminescence thermometry and photochromic and ferroelectric properties

JT Chen, TD Zhou, WB Sun - Dalton Transactions, 2023 - pubs.rsc.org
Lanthanide-based single-molecule magnets (SMMs) have captivated the attention of
researchers due to their great potential application in quantum information processing …

Syntheses of new di-nuclear and tetra-nuclear lanthanide 9-anthracenecarboxylates: Magnetocaloric effect, slow magnetic relaxation and luminescent properties

X Liu, R Yang, L Zhang, J Zhou, C Huang, H Zou… - Journal of Rare …, 2024 - Elsevier
Lanthanide complex-based materials with magnetic and luminescent properties have
received a great deal of attention, owing to their importantly potential applications in diverse …

Utilization of diamagnetic Zn (II) ion to boost the anisotropic nature of Ln (III) ion in heterodinuclear Zn (II)–Ln (III) single‐molecule magnets

S Roy, P Shukla, R Kumar, SC Sahoo… - Applied …, 2022 - Wiley Online Library
A series of dimetallic ZnII–LnIII compounds of general formulae [LnZn (L) 3 (NO3) 2]·
2CH3OH (LnIII= DyIII (1), TbIII (2), GdIII (3)) was prepared by stepwise reaction of …

There is nothing wrong with being soft: using sulfur ligands to increase axiality in a Dy (iii) single-ion magnet

AB Canaj, S Dey, O Céspedes, C Wilson… - Chemical …, 2020 - pubs.rsc.org
A new air-stable sulfur-ligated Dy (III) single-ion magnet has been successfully isolated with
Ueff= 638 K and hysteresis loops open up to 7 K. In silico studies show that the S co-ligands …

Slow relaxation in doped coordination polymers and dimers based on lanthanoids and anilato ligands

A Hernández-Paredes, C Cerezo-Navarrete… - Polyhedron, 2019 - Elsevier
In this work we report the synthesis, structure and magnetic properties of two lanthanoid
based coordination polymers (CP) and two dimers prepared with two derivatives of the 2, 5 …

Effect of diamagnetic Zn (ii) ions on the SMM properties of a series of trinuclear ZnDy 2 and tetranuclear Zn 2 Dy 2 (Ln III= Dy, Tb, Gd) complexes: combined …

P Shukla, I Tarannum, S Roy, A Rajput, P Lama… - Dalton …, 2024 - pubs.rsc.org
To study the effect of diamagnetic ions on magnetic interactions, utilizing a compartmental
ligand (Z)-2-(hydroxymethyl)-4-methyl-6-((quinolin-8-ylimino) methyl) phenol (LH2), two …

Two temperature-dependent 2D heterometallic Cd (II)–Dy (III) coordination polymers exhibiting slow magnetic relaxation and luminescence properties

Z Li, J Bu, R Zhang, C Zhang, D Wu, B Zhai - Journal of Rare Earths, 2023 - Elsevier
Two unique two-dimensional (2D) Cd (II)–Dy (III) heterometallic coordination
polymers,{[DyCd (HPMA)(PMA) 2 (H 2 O) 4]· 2H 2 O} n (1) and [DyCd (PAA)(PMA) 2 (H 2 O) …

From field-induced to zero-field SMMs associated with open/closed structures of bis (ZnDy) tetranuclear complexes: a combined magnetic, theoretical and optical …

A Zabala-Lekuona, XL de Pariza, IF Díaz-Ortega… - Dalton …, 2024 - pubs.rsc.org
We have prepared a bis (compartmental) Mannich base ligand H4L (1, 4, 8, 11-tetraaza-1, 4,
8, 11-tetrakis (2-hydroxy-3-methoxy-5-methylbenzyl) cyclotetradecane) specifically designed …