Pro-aromatic and anti-aromatic π-conjugated molecules: an irresistible wish to be diradicals
Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …
Zethrenes, Extended p-Quinodimethanes, and Periacenes with a Singlet Biradical Ground State
Conspectus Researchers have studied polycyclic aromatic hydrocarbons (PAHs) for more
than 100 years, and most PAHs in the neutral state reported so far have a closed-shell …
than 100 years, and most PAHs in the neutral state reported so far have a closed-shell …
Boron-containing organic diradicaloids: dynamically modulating singlet diradical character by lewis acid–base coordination
J Guo, Y Yang, C Dou, Y Wang - Journal of the American …, 2021 - ACS Publications
Organic diradicaloids have unique open-shell structures and properties and promising
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …
applications in organic electronics and spintronics. Incorporation of heteroatoms is an …
Diindeno-fusion of an anthracene as a design strategy for stable organic biradicals
GE Rudebusch, JL Zafra, K Jorner, K Fukuda… - Nature Chemistry, 2016 - nature.com
The consequence of unpaired electrons in organic molecules has fascinated and
confounded chemists for over a century. The study of open-shell molecules has been …
confounded chemists for over a century. The study of open-shell molecules has been …
From open-shell singlet diradicaloids to polyradicaloids
In this Feature Article, we highlight our recent efforts toward stable open-shell singlet
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …
Polycyclic aromatic hydrocarbon-based organic semiconductors: ring-closing synthesis and optoelectronic properties
Q Li, Y Zhang, Z Xie, Y Zhen, W Hu… - Journal of Materials …, 2022 - pubs.rsc.org
Polycyclic aromatic hydrocarbons (PAHs) as a typical class of organic semiconductors
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …
demonstrate unique optical, electrical, magnetic and other interesting properties due to their …
Explorations of the indenofluorenes and expanded quinoidal analogues
CK Frederickson, BD Rose… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Highly conjugated hydrocarbons have attracted interest for use as active
materials in electronic devices such as organic field effect transistors (OFET) and organic …
materials in electronic devices such as organic field effect transistors (OFET) and organic …
Construction of heptagon‐containing molecular nanocarbons
Chaolumen, IA Stepek, KE Yamada… - Angewandte Chemie …, 2021 - Wiley Online Library
Molecular nanocarbons containing heptagonal rings have attracted increasing interest due
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …
to their dynamic behavior, electronic properties, aromaticity, and solid‐state packing …
Breathing new life into nonalternant hydrocarbon chemistry: Syntheses and properties of polycyclic hydrocarbons containing azulene, pentalene, and heptalene …
A Konishi, M Yasuda - Chemistry Letters, 2021 - academic.oup.com
Abstract Azulene 1, pentalene 2, and heptalene 3 are classical nonalternant hydrocarbons.
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Their fascinating π-frameworks, consecutive arrangements of odd-membered carbocycles …
Diradical B/N‐Doped Polycyclic Hydrocarbons
J Guo, Z Li, X Tian, T Zhang, Y Wang… - Angewandte …, 2023 - Wiley Online Library
Heterocyclic diradicaloids with atom‐precise control over open‐shell nature are promising
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …
materials for organic electronics and spintronics. Herein, we disclose quinoidal π‐extension …