Recent Achievements on Functionalization within closo‐Decahydrodecaborate [B10H10]2− Clusters

N Mahfouz, FA Ghaida, Z El Hajj, M Diab… - …, 2022 - Wiley Online Library
Abstract Closo‐decahydrodecaborate anion,[B10H10] 2−, is one of the most notable clusters
in the family of hydroborates, partly attributed to its unique electronic structure and its …

[B10H10]2– Nanoclusters Covalently Immobilized to Hybrid SiO2 Aerogels for Slow Neutron Shielding Applications

KE Yorov, AP Zhdanov, RK Kamilov… - ACS Applied Nano …, 2022 - ACS Publications
An alkoxysilane derivative bearing a 10-vertex closo-decaborate nanocluster (B10H102–)
was successfully synthesized and immobilized in a SiO2 aerogel matrix. closo-Decaborate …

Grafting of Anionic Decahydro-Closo-Decaborate Clusters on Keggin and Dawson-Type Polyoxometalates: Syntheses, Studies in Solution, DFT Calculations and …

M Diab, A Mateo, J El Cheikh, Z El Hajj, M Haouas… - Molecules, 2022 - mdpi.com
Herein we report the synthesis of a new class of compounds associating Keggin and
Dawson-type Polyoxometalates (POMs) with a derivative of the anionic decahydro-closo …

Clean-activation of the B–H bond in closo-decahydrodecaborate [B10H10] 2− anion via soft-route

Z Laila, O Yazbeck, F Abi Ghaida, M Diab… - Journal of …, 2020 - Elsevier
Abstract Series of closo-decaborate (NH 4) 2 [B 10 H 10] derivatives were prepared by their
direct reaction with ligand L (alcohols or nitriles) via an auto-catalyzed reaction with NH 4+ …

N-Borylated Hydroxylamines [B12H11NH2OH] as a Novel Type of Substituted Derivative of the closo-Dodecaborate Anion

AV Nelyubin, NA Selivanov, AY Bykov… - Russian Journal of …, 2020 - Springer
Methods for the preparation of N-substituted hydroxylamine [B 12 H 11 NH 2 OH]–have
been developed and optimized. The possibility of using two synthetic methods has been …

Playing with the Chaotropic Effect to Improve the Encapsulation of Decaborate Clusters within Cyclodextrins

Z El Hajj, S Calancea, M Haouas, D Landy… - Journal of Cluster …, 2024 - Springer
This paper deals with the formation of host-guest systems between α-, β-and γ-cyclodextrins
and the anionic cluster [B10H9NCCH3]-. The inclusion processes within cyclodextrins were …

Encapsulation of Chaotropic closo‐Decahydrodecaborate Clusters Within Cyclodextrins: Synthesis, Solution Studies, and DFT Calculations

M Diab, S Floquet, M Haouas… - European Journal of …, 2019 - Wiley Online Library
This paper deals with the formation of host‐guest systems between cyclodextrins and the
closo‐decahydrodecaborate cluster. The inclusion processes, although involving weak …

Synthesis and Physicochemical Properties of C-Borylated Esters Based on the closo-Decaborate Anion

IN Klyukin, NA Selivanov, AY Bykov… - Russian Journal of …, 2020 - Springer
The interaction of the monocarbonyl derivative of the closo-decaborate anion [2-B 10 H 9
CO]–with O-nucleophiles has been considered. It has been found that primary, secondary …

Multifunctional Silica Nanoparticles Modified via Silylated‐Decaborate Precursors

F Abi-Ghaida, S Clément, A Safa… - Journal of …, 2015 - Wiley Online Library
A new class of multifunctional silica nanoparticles carrying boron clusters (10‐vertex closo‐
decaborate) and incorporating luminescent centers (fluorescein) has been developed as …

Hydrolysis of nitrilium derivatives of the closo-decaborate anion [2-B10H9(N≡CR)] (R = CH3, C2H5, C(CH3)3, or C6H5)

AP Zhdanov, AY Bykov, AS Kubasov… - Russian Journal of …, 2017 - Springer
Reaction of tetrabutylammonium salts of [2-B 10 H 9 (N≡ CR)]–(R= CH 3, C 2 H 5, C (CH 3)
3, or C 6 H 5) anions with water results in N-borylated iminols (Bu 4 N)[2-B 10 H 9 NH= C …