Structural, spectroscopic, and reactivity models for the manganese catalases

AJ Wu, JE Penner-Hahn, VL Pecoraro - Chemical Reviews, 2004 - ACS Publications
Given the well-defined enzymology of the manganese catalases and recent advances in the
structural biology of these proteins, this is an excellent area for corroborative modeling of the …

Pulsed and parallel-polarization EPR characterization of the photosystem II oxygen-evolving complex

RD Britt, JM Peloquin… - Annual Review of …, 2000 - annualreviews.org
▪ Abstract Photosystem II uses visible light to drive the oxidation of water, resulting in
bioactivated electrons and protons, with the production of molecular oxygen as a byproduct …

[图书][B] Handbook on metalloproteins

I Bertini, A Sigel - 2001 - taylorfrancis.com
This Handbook on Metalloproteins focuses on the available structural information of proteins
and their metal ion coordination spheres. It centers on the metal ions indispensable for life …

High-spin Mn–oxo complexes and their relevance to the oxygen-evolving complex within photosystem II

R Gupta, T Taguchi, B Lassalle-Kaiser… - Proceedings of the …, 2015 - National Acad Sciences
The structural and electronic properties of a series of manganese complexes with terminal
oxido ligands are described. The complexes span three different oxidation states at the …

EPR–ENDOR Characterization of (17O, 1H, 2H) Water in Manganese Catalase and Its Relevance to the Oxygen-Evolving Complex of Photosystem II

IL McConnell, VM Grigoryants… - Journal of the …, 2012 - ACS Publications
The synthesis of efficient water-oxidation catalysts demands insight into the only known,
naturally occurring water-oxidation catalyst, the oxygen-evolving complex (OEC) of …

Stabilization of Mn (II) and Mn (III) in mononuclear complexes derived from tridentate ligands with N2O donors: Synthesis, crystal structure, superoxide dismutase …

K Ghosh, N Tyagi, P Kumar, UP Singh… - Journal of inorganic …, 2010 - Elsevier
A new family of tridentate ligands PhimpH (2-((2-phenyl-2-(pyridin-2-yl) hydazono) methyl)
phenol), N–PhimpH (2-((2-phenyl-2-(pyridin-2-yl) hydrazono) methyl) napthalen-1-ol), Me …

Synthesis, structure, and DNA-binding properties of manganese(II) and zinc(II) complexes with tris(N-methylbenzimidazol-2-ylmethyl)amine ligand

HL Wu, K Li, T Sun, F Kou, F Jia, JK Yuan, B Liu… - Transition Metal …, 2011 - Springer
Abstract Tris (N-methylbenzimidazol-2-ylmethyl) amine (Mentb) and its two complexes,[Mn
(Mentb)(DMF)(H 2 O)](pic) 2 1 and [Zn (Mentb)(pic)](pic) 2 (pic= picrate), have been …

Reaction landscape of a pentadentate N5-ligated Mn II complex with O 2˙− and H 2 O 2 includes conversion of a peroxomanganese (iii) adduct to a bis (μ-oxo) …

DF Leto, S Chattopadhyay, VW Day, TA Jackson - Dalton Transactions, 2013 - pubs.rsc.org
Herein we describe the chemical reactivity of the mononuclear [MnII (N4py)(OTf)](OTf)(1)
complex with hydrogen peroxide and superoxide. Treatment of 1 with one equivalent …

Dimanganese catalase—spectroscopic parameters from broken-symmetry density functional theory of the superoxidized MnIII/MnIV state

S Sinnecker, F Neese, W Lubitz - JBIC Journal of Biological Inorganic …, 2005 - Springer
Broken-symmetry density functional theory was used to study the catalytic center of
manganese catalase in the superoxidized Mn III/Mn IV state. Heisenberg exchange coupling …

Validation of broken-symmetry density functional methods for the calculation of electron paramagnetic resonance parameters of dinuclear mixed-valence MnIVMnIII …

S Schinzel, M Kaupp - Canadian Journal of Chemistry, 2009 - cdnsciencepub.com
. The EPR parameters of a series of dinuclear manganese (III, IV) complexes with mono (μ-
oxo), bis (μ-oxo),(μ-oxo)(μ-carboxylato), bis (μ-oxo)(μ-carboxylato), and (μ-oxo) bis (μ …