Hydrogenase enzymes and their synthetic models: the role of metal hydrides
Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …
Hydrogenases
The reaction takes place at a specialized metal center that dramatically increases the acidity
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
of H2 and leads to a heterolytic splitting of the molecule which is strongly accelerated by the …
Hydrogen evolution catalyzed by cobaloximes
JL Dempsey, BS Brunschwig, JR Winkler… - Accounts of chemical …, 2009 - ACS Publications
Natural photosynthesis uses sunlight to drive the conversion of energy-poor molecules
(H2O, CO2) to energy-rich ones (O2,(CH2O) n). Scientists are working hard to develop …
(H2O, CO2) to energy-rich ones (O2,(CH2O) n). Scientists are working hard to develop …
Structural and functional analogues of the active sites of the [Fe]-,[NiFe]-, and [FeFe]-hydrogenases
C Tard, CJ Pickett - Chemical reviews, 2009 - ACS Publications
This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …
functional analogues of the three classes of hydrogenases. This chemistry has grown …
Hydrogen-oxidizing bacteria and their applications in resource recovery and pollutant removal
L Lin, H Huang, X Zhang, L Dong, Y Chen - Science of The Total …, 2022 - Elsevier
Hydrogen oxidizing bacteria (HOB), a type of chemoautotroph, are a group of bacteria from
different genera that share the ability to oxidize H 2 and fix CO 2 to provide energy and …
different genera that share the ability to oxidize H 2 and fix CO 2 to provide energy and …
DFT study on structure, electronic properties, and reactivity of cis-isomers of [(NC5H4-S)2Fe(CO)2]
CA Mebi - Journal of Chemical Sciences, 2011 - Springer
Three cis-isomers of [(NC 5 H 4-S) 2 Fe (CO) 2], models for the active site of [Fe]
hydrogenase, have been examined by computational method at DFT B3LYP/6–311+ G (d …
hydrogenase, have been examined by computational method at DFT B3LYP/6–311+ G (d …
Hydrogenase enzymes: recent structural studies and active site models
DM Heinekey - Journal of Organometallic Chemistry, 2009 - Elsevier
Hydrogenase enzymes: Recent structural studies and active site models - ScienceDirect
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Hydrogenases and oxygen
MT Stiebritz, M Reiher - Chemical science, 2012 - pubs.rsc.org
Hydrogenases represent a heterogeneous group of enzymes consisting of three
evolutionary unrelated classes, ie [NiFe],[FeFe] and [Fe] hydrogenases. They allow the uni …
evolutionary unrelated classes, ie [NiFe],[FeFe] and [Fe] hydrogenases. They allow the uni …
Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [57Fe2(adt)(CN)2(CO)4]2–
R Gilbert-Wilson, JF Siebel… - Journal of the …, 2015 - ACS Publications
The preparation and spectroscopic characterization of a CO-inhibited [FeFe] hydrogenase
with a selectively 57Fe-labeled binuclear subsite is described. The precursor [57Fe2 …
with a selectively 57Fe-labeled binuclear subsite is described. The precursor [57Fe2 …
A personal account on 25 years of scientific literature on [FeFe]-hydrogenase
JW Sidabras, ST Stripp - JBIC Journal of Biological Inorganic Chemistry, 2023 - Springer
Abstract [FeFe]-hydrogenases are gas-processing metalloenzymes that catalyze H2
oxidation and proton reduction (H2 release) in microorganisms. Their high turnover …
oxidation and proton reduction (H2 release) in microorganisms. Their high turnover …