Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA)
Fluorochemicals (FCs) are oxidatively recalcitrant, environmentally persistent, and resistant
to most conventional treatment technologies. FCs have unique physiochemical properties …
to most conventional treatment technologies. FCs have unique physiochemical properties …
Reductive defluorination of aqueous perfluorinated alkyl surfactants: effects of ionic headgroup and chain length
Perfluorinated chemicals (PFCs) are distributed throughout the environment. In the case of
perfluorinated alkyl carboxylates and sulfonates, they can be classified as persistent organic …
perfluorinated alkyl carboxylates and sulfonates, they can be classified as persistent organic …
Recent developments in the chemistry of organic perfluoro hypofluorites
V Francesco, M Sansotera, W Navarrini - Journal of Fluorine Chemistry, 2013 - Elsevier
Recent findings in the synthesis of perfluoro-hypofluorites, their reactivity and their use in the
preparation of important perfluoro monomers are herein summarized and analyzed. The …
preparation of important perfluoro monomers are herein summarized and analyzed. The …
Electron spin resonance. Part 67. Oxidation of aliphatic sulphides and sulphoxides by the sulphate radical anion (SO 4–˙) and of aliphatic radicals by the …
MJ Davies, BC Gilbert, ROC Norman - Journal of the Chemical Society …, 1984 - pubs.rsc.org
Esr experiments employing in situ photolytic decomposition of the peroxydisulphate anion
(S2O82–) have been carried out to study the reaction of SO4–˙ with aliphatic sulphides and …
(S2O82–) have been carried out to study the reaction of SO4–˙ with aliphatic sulphides and …
Photocatalytic activity of TiO2-embedded fluorinated transparent coating for oxidation of hydrosoluble pollutants in turbid suspensions
F Persico, M Sansotera, CL Bianchi, C Cavallotti… - Applied Catalysis B …, 2015 - Elsevier
The photodegradative activity of titanium dioxide immobilized into a multilayered transparent
fluoropolymeric matrix was studied. The photoactive coating was developed by applying a …
fluoropolymeric matrix was studied. The photoactive coating was developed by applying a …
Substituent effects in a series of 1, 7-C 60 (RF) 2 compounds (RF= CF 3, C 2 F 5, nC 3 F 7, iC 3 F 7, nC 4 F 9, sC 4 F 9, nC 8 F 17): electron affinities, reduction …
IV Kuvychko, JB Whitaker, BW Larson, TC Folsom… - Chemical …, 2012 - pubs.rsc.org
A series of seven structurally-similar compounds with different pairs of RF groups were
prepared, characterized spectroscopically, and studied by electrochemical methods (cyclic …
prepared, characterized spectroscopically, and studied by electrochemical methods (cyclic …
Reduction of polyfluorinated compounds
C Combellas, F Kanoufi, A Thiébault - The Journal of Physical …, 2003 - ACS Publications
Reduction of perfluoroalkylphenylcyanides and perfluorodecalin was investigated by cyclic
voltammetry and interpreted by intramolecular dissociative electron-transfer models, taking …
voltammetry and interpreted by intramolecular dissociative electron-transfer models, taking …
Surface reactivity from electrochemical lithography: illustration in the steady-state reductive etching of perfluorinated surfaces
The scanning electrochemical microscope (SECM) in the lithographic mode is used to
assess quantitatively, from both theoretical and experimental points of view, the kinetics of …
assess quantitatively, from both theoretical and experimental points of view, the kinetics of …
Reductive defluorination of graphite monofluoride by weak, non-nucleophilic reductants reveals low-lying electron-accepting sites
Graphite monofluoride (GF) can undergo reductive defluorination in the presence of weak,
non-nucleophilic reductants. This leads to a new approach to GF–polyaniline composites as …
non-nucleophilic reductants. This leads to a new approach to GF–polyaniline composites as …
Conformational dynamics of triradical nitroxides as studied by EPR
C Corvaja, M De Marchi, A Toffoletti - Applied Magnetic Resonance, 1997 - Springer
The EPR spectra of a flexible nitroxide triradical are recorded in a large temperature range.
A detailed analysis of the spectral features is performed and the spectra are compared with …
A detailed analysis of the spectral features is performed and the spectra are compared with …