Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Diverse emission properties of transition metal complexes beyond exclusive single phosphorescence and their wide applications

K Li, Y Chen, J Wang, C Yang - Coordination Chemistry Reviews, 2021 - Elsevier
Luminescence properties and excited state reactivities of photoactive transition metal
complexes have been harnessed for various applications in the fields of electroluminescent …

Selective photocatalytic C–F borylation of polyfluoroarenes by Rh/Ni dual catalysis providing valuable fluorinated arylboronate esters

YM Tian, XN Guo, MW Kuntze-Fechner… - Journal of the …, 2018 - ACS Publications
A highly selective and general photocatalytic C–F borylation protocol that employs a
rhodium biphenyl complex as a triplet sensitizer and the nickel catalyst [Ni (IMes) 2](IMes= 1 …

Experimental and theoretical studies of the photophysical properties of 2-and 2, 7-functionalized pyrene derivatives

AG Crawford, AD Dwyer, Z Liu, A Steffen… - Journal of the …, 2011 - ACS Publications
Pyrene derivatives substituted at the 2-and 2, 7-positions are shown to display a set of
photophysical properties different from those of derivatives substituted at the 1-position. It …

Turn‐on fluorescence in tetra‐NHC ligands by rigidification through metal complexation: an alternative to aggregation‐induced emission

N Sinha, L Stegemann, TTY Tan… - Angewandte Chemie …, 2017 - Wiley Online Library
Two tetraphenylethylene (TPE) bridged tetraimidazolium salts,[H4L‐Et](PF6) 4 and [H4L‐
Bu](PF6) 4, were used as precursors for the synthesis of the dinuclear AgI and AuI …

Metal-containing triarylboron compounds for optoelectronic applications

ZM Hudson, S Wang - Dalton Transactions, 2011 - pubs.rsc.org
Triarylboranes have recently emerged as a powerful new class of electron acceptors with
great potential as optoelectronic materials. The empty pz orbital on the boron centre …

Enhancing phosphorescence and electrophosphorescence efficiency of cyclometalated Pt (II) compounds with triarylboron

ZM Hudson, C Sun, MG Helander… - Advanced Functional …, 2010 - Wiley Online Library
A synthetic strategy for the preparation of cyclometalated platinum (II) acetylacetonate (acac)
complexes functionalized with triarylboron is achieved. This method is used to synthesize a …

An insight into fluorescent transition metal complexes

YY Chia, MG Tay - Dalton Transactions, 2014 - pubs.rsc.org
The emission from transition metal complexes is usually produced from triplet excited states.
Owing to strong spin–orbit coupling (SOC), the fast conversion of singlet to triplet excited …

Dibenzometallacyclopentadienes, boroles and selected transition metal and main group heterocyclopentadienes: Synthesis, catalytic and optical properties

A Steffen, RM Ward, WD Jones, TB Marder - Coordination Chemistry …, 2010 - Elsevier
The review discusses the synthesis, structures and properties of transition metal and main-
group containing heterocyclopentadienes, with particular focus on …

Organoboron compounds with morphology-dependent NIR emissions and dual-channel fluorescent ON/OFF switching

X Cheng, D Li, Z Zhang, H Zhang, Y Wang - Organic letters, 2014 - ACS Publications
A novel family of organoboron compounds 1–4 with bright near-infrared (NIR) emissions in
the crystalline state was synthesized. They show a morphology-dependent emission “ON” …