Bioinspired framework catalysts: From enzyme immobilization to biomimetic catalysis
Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …
and selectivity. However, the structural complexity and vulnerability hamper the application …
Construction and application of base-stable MOFs: a critical review
Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …
Understanding the inter-site distance effect in single-atom catalysts for oxygen electroreduction
Regulating the site density of single-atom catalysts (SACs) promotes the potential to
remarkably improve the performance of electrocatalysis, such as the oxygen reduction …
remarkably improve the performance of electrocatalysis, such as the oxygen reduction …
Inter‐Metal Interaction with a Threshold Effect in NiCu Dual‐Atom Catalysts for CO2 Electroreduction
Dual‐atom catalysts (DACs) have become an emerging platform to provide more flexible
active sites for electrocatalytic reactions with multi‐electron/proton transfer, such as the CO2 …
active sites for electrocatalytic reactions with multi‐electron/proton transfer, such as the CO2 …
Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
Application of Conductive MOF in Zinc‐Based Batteries
The use of conductive MOFs (c‐MOFs) in zinc‐based batteries has been a popular research
direction. Zinc‐based batteries are widely used with the advantages of high specific capacity …
direction. Zinc‐based batteries are widely used with the advantages of high specific capacity …
Atomic-level design of metalloenzyme-like active pockets in metal–organic frameworks for bioinspired catalysis
Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …
Large‐area free‐standing metalloporphyrin‐based covalent organic framework films by liquid‐air interfacial polymerization for oxygen electrocatalysis
Synthesizing large‐area free‐standing covalent organic framework (COF) films is of vital
importance for their applications but is still a big challenge. Herein, we reported the …
importance for their applications but is still a big challenge. Herein, we reported the …
Dual‐metal atom electrocatalysts: theory, synthesis, characterization, and applications
Electrochemical clean energy conversion and the production of sustainable chemicals are
critical in the journey to realizing a truly sustainable society. To progress electrochemical …
critical in the journey to realizing a truly sustainable society. To progress electrochemical …
Molecular Catalysis of Energy Relevance in Metal–Organic Frameworks: From Higher Coordination Sphere to System Effects
NF Suremann, BD McCarthy, W Gschwind… - Chemical …, 2023 - ACS Publications
The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …