Enzymatic catalysis has fueled considerable interest from chemists due to its high efficiency
and selectivity. However, the structural complexity and vulnerability hamper the application …

Metal–organic frameworks (MOFs) are a new class of porous crystalline materials
constructed from organic ligands and metal ions/clusters. Owing to their unique advantages …

Regulating the site density of single-atom catalysts (SACs) promotes the potential to
remarkably improve the performance of electrocatalysis, such as the oxygen reduction …

Dual‐atom catalysts (DACs) have become an emerging platform to provide more flexible
active sites for electrocatalytic reactions with multi‐electron/proton transfer, such as the CO2 …

Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

The use of conductive MOFs (c‐MOFs) in zinc‐based batteries has been a popular research
direction. Zinc‐based batteries are widely used with the advantages of high specific capacity …

Natural metalloenzymes with astonishing reaction activity and specificity underpin essential
life transformations. Nevertheless, enzymes only operate under mild conditions to keep …

Synthesizing large‐area free‐standing covalent organic framework (COF) films is of vital
importance for their applications but is still a big challenge. Herein, we reported the …

Electrochemical clean energy conversion and the production of sustainable chemicals are
critical in the journey to realizing a truly sustainable society. To progress electrochemical …

The modularity and synthetic flexibility of metal–organic frameworks (MOFs) have provoked
analogies with enzymes, and even the term MOFzymes has been coined. In this review, we …