Azobenzene is a well‐known derivative of stimulus‐responsive molecular switches and has
shown superior performance as a functional material in biomedical applications. The results …

Transition-metal complexes, which exhibit photobasic properties, are highly promising for
chemical applications where the proton abstraction represents one key step. Photobases …

Chemoselective modification of complex biomolecules has become a cornerstone of
chemical biology. Despite the exciting developments of the past two decades, the demand …

Three visible‐light responsive photoswitches are reported, azobis (1‐methyl‐
benzimidazole)(1), azobis (benzoxazole)(2) and azobis (benzothiazole)(3). Photostationary …

Aryl transfer reactions from arenediazonium salts have started to make their impact in
chemical biology with initial forays in the arena of arylative modifications and bio …

A metal-free, light-induced regiodivergent functionalization of α, β-unsaturated amides with
aryltriazenes under ambient conditions was developed. The visible light and B (C6F5) 3 …

The first photoswitchable bimetallic gold catalysts based on an azobenzene backbone have
been synthesized and their catalytic properties have been investigated. In the intramolecular …

A new triazene ligand was prepared by the reaction of the bulky aryl azide, TerMesN3,(2, 6-
bis (2, 4, 6-trimethylphenyl) phenyl azide), with the bulky N-heterocyclic carbene (NHC), SIPr …

The synthetic utility of triazenes rests on the fact that the triazene function can be cleaved by
Brønsted or Lewis acids, liberating diazonium compounds. However, the preferred …

This work describes the development of phenyl diazenyl piperidine triazene derivatives that
can be activated to release aryl diazonium ions for labeling of proteins using light. These …