Frustrated radical pairs in organic synthesis
Frustrated radical pairs (FRPs) describe the phenomenon that two distinct radicals─ which
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …
would otherwise annihilate each other to form a closed-shell covalent adduct─ can coexist …
Metallomimetic chemistry of boron
The study of main-group molecules that behave and react similarly to transition-metal (TM)
complexes has attracted significant interest in recent decades. Most notably, the attractive …
complexes has attracted significant interest in recent decades. Most notably, the attractive …
Reactivity models of hydrogen activation by frustrated Lewis pairs: synergistic electron transfers or polarization by electric field?
Two alternative qualitative reactivity models have recently been proposed to interpret the
facile heterolytic cleavage of H2 by frustrated Lewis pairs (FLPs). Both models assume that …
facile heterolytic cleavage of H2 by frustrated Lewis pairs (FLPs). Both models assume that …
Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2 Activation and the Role of Acid−Base Properties
The acid− base strengths of recently reported frustrated Lewis pairs and their relation with
the thermodynamic feasibility of heterolytic hydrogen splitting reactions are analyzed in …
the thermodynamic feasibility of heterolytic hydrogen splitting reactions are analyzed in …
A radical mechanism for frustrated Lewis pair reactivity
Summary The frustrated Lewis pairs (FLPs) derived from tBu 3 P and E (C 6 F 5) 3 (E= B, Al)
react with pO 2 C 6 Cl 4 and Ph 3 SnH to give [tBu 3 POC 6 Cl 4 OE (C 6 F 5) 3](E= B 1, Al …
react with pO 2 C 6 Cl 4 and Ph 3 SnH to give [tBu 3 POC 6 Cl 4 OE (C 6 F 5) 3](E= B 1, Al …
On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration
TA Rokob, A Hamza, A Stirling… - Journal of the American …, 2009 - ACS Publications
The reaction mechanism for the transition metal free direct hydrogenation of bulky imines
catalyzed by the Lewis acid B (C6F5) 3 is investigated in detail by quantum chemical …
catalyzed by the Lewis acid B (C6F5) 3 is investigated in detail by quantum chemical …
Reactions of phosphorus/boron frustrated Lewis pairs with SO 2
M Sajid, A Klose, B Birkmann, L Liang, B Schirmer… - Chemical …, 2013 - pubs.rsc.org
The frustrated Lewis pair tBu3P/B (C6F5) 3 (1) readily adds SO2 to yield the zwitterionic
adduct tBu3P+–S (O)–OB−(C6F5) 3 (3). A series of intramolecular vicinal P/B FLPs Mes2P …
adduct tBu3P+–S (O)–OB−(C6F5) 3 (3). A series of intramolecular vicinal P/B FLPs Mes2P …
Synthesis of an isolable bis (silylene)-stabilized silylone and its reactivity toward small gaseous molecules
The first bis (N-heterocyclic silylene)-stabilized zero-valent silicon compound,[SiII (Xant) SiII]
Si0 (4, Xant= 9, 9-dimethyl-xanthene-4, 5-diyl), has been synthesized via the reduction of the …
Si0 (4, Xant= 9, 9-dimethyl-xanthene-4, 5-diyl), has been synthesized via the reduction of the …
Frustrated Lewis pairs: bonding, reactivity, and applications
The outstanding capability of Frustrated Lewis Pair (FLP) catalysts to activate small
molecules has gained significant attention in recent times. Reactivity of FLP is further …
molecules has gained significant attention in recent times. Reactivity of FLP is further …
Frustrated Lewis Pair Behavior of Intermolecular Amine/B(C6F5)3 Pairs
Reactions of N, N-dimethylaniline, N-isopropylaniline, 1, 4-C6H4 (CH2NH t Bu) 2, and
benzyldimethylamine with the Lewis acid B (C6F5) 3 have been studied. In the case of N, N …
benzyldimethylamine with the Lewis acid B (C6F5) 3 have been studied. In the case of N, N …