Abstract 3d–4f heterometallic discrete complexes have enjoyed increasing attraction in
recent decades because of their potential advantages to create new single-molecule …

There has been a rapid expansion in the use of molecular magnets for both low-and ultra
low-temperature cooling applications in recent years, and here we review the chemical …

This review outlines recent advances in the design of 3d-, 4f-, and 3d–4f type magnetic
molecules for use as excellent cryogenic magnetic coolants based on the magnetocaloric …

Zero-dimensional cluster complexes and coordination polymers for magnetic refrigeration
have attracted great interest in the last decade. In-situ synthesis is a widely-used method to …

The promising potential applications, such as information processing and storage or
molecular spintronics, of single-molecule magnets (SMMs) have spurred on the research of …

A record anisotropy barrier (319 cm− 1) for all d‐f complexes was observed for a unique FeII‐
DyIII‐FeII single‐molecule magnet (SMM), which possesses two asymmetric and distorted …

A series of dinuclear Dy (III) compounds with the general formula [Dy2 (μ2-anthc) 4 (anthc) 2
(L) 2](anthc–= 9-anthracenecarboxylate, L= 2, 2′-bipyridyl (1), 1, 10-phenanthroline (2) …

Coordination polymers serving as molecular magnetic refrigerants have been attracting
great interest. In particular, coordination cluster compounds that demonstrate their apparent …

The use of the [FeIII (AA)(CN) 4]− complex anion as metalloligand towards the preformed
[CuII (valpn) LnIII] 3+ or [NiII (valpn) LnIII] 3+ heterometallic complex cations (AA= 2, 2 …

Magnetic cooling has aroused great interest in cryogenic research due to its high energy
efficiency. Due to the large magnetic moment and completely quenched orbital momentum …