Guiding the design of heterogeneous electrode microstructures for Li‐ion batteries: microscopic imaging, predictive modeling, and machine learning

H Xu, J Zhu, DP Finegan, H Zhao, X Lu… - Advanced Energy …, 2021 - Wiley Online Library
Electrochemical and mechanical properties of lithium‐ion battery materials are heavily
dependent on their 3D microstructure characteristics. A quantitative understanding of the …

Computational insights into ionic conductivity of transition metal electrode materials for metal-ion batteries-A review

DA Aksyonov, AO Boev, SS Fedotov, AM Abakumov - Solid State Ionics, 2023 - Elsevier
Charge/discharge rates and low-temperature performance of metal-ion batteries are strongly
affected by the ionic conductivity of transition metal intercalation materials used in …

Kinetic limitations in single‐crystal high‐nickel cathodes

M Ge, S Wi, X Liu, J Bai, S Ehrlich, D Lu… - Angewandte Chemie …, 2021 - Wiley Online Library
High‐nickel cathodes attract immense interest for use in lithium‐ion batteries to boost Li‐
storage capacity while reducing cost. For overcoming the intergranular‐cracking issue in …

Energy storage through intercalation reactions: electrodes for rechargeable batteries

RC Massé, C Liu, Y Li, L Mai, G Cao - National Science Review, 2017 - academic.oup.com
Electrochemical energy storage has been an important enabling technology for modern
electronics of all kinds, and will grow in importance as more electric vehicles and grid-scale …

Intercalation kinetics in multiphase-layered materials

RB Smith, E Khoo, MZ Bazant - The Journal of Physical Chemistry …, 2017 - ACS Publications
Many intercalation compounds possess layered structures or interpenetrating lattices that
enable phase separation into three or more stable phases, or “stages,” driven by competing …

Rate Dependent Performance Related to Crystal Structure Evolution of Na0.67Mn0.8Mg0.2O2 in a Sodium-Ion Battery

N Sharma, N Tapia-Ruiz, G Singh… - Chemistry of …, 2015 - ACS Publications
Sodium-ion batteries are considered as a favorable alternative to the widely used lithium-ion
batteries for applications such as grid-scale energy storage. However, to meet the energy …

Entering Voltage Hysteresis in Phase‐Separating Materials: Revealing the Electrochemical Signature of the Intraparticle Phase‐Separated State

T Katrašnik, J Moškon, K Zelič, I Mele… - Advanced …, 2023 - Wiley Online Library
Hysteresis is a general phenomenon regularly observed in various materials. Usually,
hysteretic behavior is an intrinsic property that cannot be circumvented in the nonequilibrium …

Explaining key properties of lithiation in -anatase Li-ion battery electrodes using phase-field modeling

NJJ De Klerk, A Vasileiadis, RB Smith, MZ Bazant… - Physical Review …, 2017 - APS
The improvement of Li-ion battery performance requires development of models that capture
the essential physics and chemistry in Li-ion battery electrode materials. Phase-field …

Deformation and stresses in solid-state composite battery cathodes

HC Yu, D Taha, T Thompson, NJ Taylor, A Drews… - Journal of Power …, 2019 - Elsevier
Differences in thermal contraction/expansion and volume changes during discharge/charge
cycles lead to internal stresses that ultimately cause degradation of solid-state composite …

The Microscopic Mechanism of Lithiation and Delithiation in the Ag/C Buffer Layer for Anode‐Free Solid‐State Batteries

F Xie, MS Diallo, H Kim, QH Tu… - Advanced Energy …, 2024 - Wiley Online Library
Lithium metal solid‐state batteries (LMSSBs) have demonstrated their high energy density
and cycling performance at high current densities in an anode‐free architecture, featuring a …