Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Ultrafast dynamics of single molecules

D Brinks, R Hildner, EMHP Van Dijk… - Chemical Society …, 2014 - pubs.rsc.org
The detection of individual molecules has found widespread application in molecular
biology, photochemistry, polymer chemistry, quantum optics and super-resolution …

Investigation of the Influence of Solute− Solvent Interactions on the Vibrational Energy Relaxation Dynamics of Large Molecules in Liquids

A Pigliucci, G Duvanel, LML Daku… - The Journal of Physical …, 2007 - ACS Publications
The influence of solute− solvent interactions on the vibrational energy relaxation dynamics
of perylene and substituted perylenes in the first singlet excited-state upon excitation with …

A femtosecond fluorescence study of vibrational relaxation and cooling dynamics of UV dyes

O Braem, TJ Penfold, A Cannizzo… - Physical Chemistry …, 2012 - pubs.rsc.org
We present a femtosecond broad-band fluorescence up-conversion study of the vibrational
relaxation dynamics of two UV chromophores, 2, 5-diphenyloxazole (PPO) and para …

Vibrational Coherences of the Photoinduced Mixed-Valent Creutz–Taube Ion Revealed by Excited State Dynamics

A Šrut, V Krewald - The Journal of Physical Chemistry A, 2023 - ACS Publications
A recent study of photoinduced mixed-valency in the one-electron reduced form (μ-pz)[RuII
(NH3) 5] 24+ of the Creutz–Taube ion used transient absorption spectroscopy with vis-NIR …

Quantifying the Relaxation Dynamics of Higher Electronic Excited States in Perylene

RJ Hudson, A Manian, CR Hall… - The Journal of …, 2023 - ACS Publications
Gating logical operations through high-lying electronic excited states presents opportunities
for developing ultrafast, subnanometer computational devices. A lack of molecular systems …

[HTML][HTML] Vibrational relaxation by methylated xanthines in solution: Insights from 2D IR spectroscopy and calculations

AT Hanes, C Grieco, RF Lalisse, CM Hadad… - The Journal of …, 2023 - pubs.aip.org
Two-dimensional infrared (2D IR) spectroscopy, infrared pump–infrared probe spectroscopy,
and density functional theory calculations were used to study vibrational relaxation by ring …

Solvent-hindered intramolecular vibrational redistribution

JT King, JM Anna, KJ Kubarych - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
Ultrafast two-dimensional infrared spectroscopy and molecular dynamics simulations of Mn2
(CO) 10 in a series of linear alcohols reveal that the rate of intramolecular vibrational …

Substitution dependent ultrafast ultraviolet energy dissipation mechanisms of plant sunscreens

X Zhao, J Luo, Y Liu, P Pandey, S Yang… - The Journal of …, 2019 - ACS Publications
An ultraviolet energy dissipation mechanism plays a critical role in the photoprotection effect
of sunscreens. In this work, we discovered substitution dependent UV energy dissipation …

Optical transient absorption experiments reveal the failure of formal kinetics in diffusion assisted electron transfer reactions

G Angulo, A Rosspeintner, B Lang… - Physical Chemistry …, 2018 - pubs.rsc.org
The ultimate goal of chemical kinetics is to understand why a given reaction is fast or not. To
this end it is necessary to count on robust and experimentally well tested theories. One of the …