Catalysis as an enabling science for sustainable polymers
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …
A circular economy approach to plastic waste
Growing environmental concerns associated with the accumulation of plastic waste in the
natural environment has incentivised considerable research into renewable alternatives …
natural environment has incentivised considerable research into renewable alternatives …
Controlling polymer stereochemistry in ring-opening polymerization: a decade of advances shaping the future of biodegradable polyesters
This review highlights recent developments in the field of biodegradable polymeric materials
intended to replace non-degradable conventional plastics, focusing on studies from the last …
intended to replace non-degradable conventional plastics, focusing on studies from the last …
Toward infinitely recyclable plastics derived from renewable cyclic esters
Plastics, used in countless consumer products that our daily lives depend on, have become
indispensable materials essential for modern life and the global economy. At the same time …
indispensable materials essential for modern life and the global economy. At the same time …
[HTML][HTML] Poly (lactic acid) stereocomplexes based molecular architectures: Synthesis and crystallization
This review presents the state of the art of complex macromolecular architectures based on
polylactide stereocomplexes (PLA-sc) from the viewpoint of synthesis and crystallization …
polylactide stereocomplexes (PLA-sc) from the viewpoint of synthesis and crystallization …
Discrete cationic complexes for ring-opening polymerization catalysis of cyclic esters and epoxides
Y Sarazin, JF Carpentier - Chemical reviews, 2015 - ACS Publications
1.1 Background Interest in ring-opening polymerization (ROP) reactions has gained
tremendous momentum in the course of the past two decades.(1) While the polymerization …
tremendous momentum in the course of the past two decades.(1) While the polymerization …
Beyond Stereoselectivity, switchable catalysis: Some of the last frontier challenges in ring‐opening polymerization of cyclic esters
SM Guillaume, E Kirillov, Y Sarazin… - … –A European Journal, 2015 - Wiley Online Library
Metal‐based catalysts and initiators have played a pivotal role in the ring‐opening
polymerization (ROP) of cyclic esters, thanks to their high activity and remarkable ability to …
polymerization (ROP) of cyclic esters, thanks to their high activity and remarkable ability to …
Recent advances in metal‐mediated stereoselective ring‐opening polymerization of functional cyclic esters towards well‐defined poly (hydroxy acid) s: from …
H Li, RM Shakaroun, SM Guillaume… - … –A European Journal, 2020 - Wiley Online Library
Poly (hydroxy acid) s are a family of biocompatible and (bio) degradable polyesters with
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …
various outcomes in different domains of application. To date, poly (hydroxy acid) s are best …
Poly (lactic acid) degradation into methyl lactate catalyzed by a well-defined Zn (II) complex
Poly (lactic acid)(PLA) was degraded to methyl lactate (Me-La) by an imino monophenolate
Zn (1) 2 catalyst in the presence of tetrahydrofuran, as the solvent, and methanol, as the …
Zn (1) 2 catalyst in the presence of tetrahydrofuran, as the solvent, and methanol, as the …
Dizinc lactide polymerization catalysts: hyperactivity by control of ligand conformation and metallic cooperativity
Understanding how to moderate and improve catalytic activity is critical to improving
degradable polymer production. Here, di‐and monozinc catalysts, coordinated by bis (imino) …
degradable polymer production. Here, di‐and monozinc catalysts, coordinated by bis (imino) …