Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
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Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox …

C Carter, Y Kratish, T Jurca, Y Gao… - Journal of the American …, 2020 - ACS Publications
A family of metal dichloride complexes having a bis-ferrocenyl-substituted pyridinediimine
ligand was systematically synthesized ((Fc2PDI) MCl2, M= Mg, Zn, Fe, and Co) and …

Electronically Strongly Coupled Divinylheterocyclic‐Bridged Diruthenium Complexes

U Pfaff, A Hildebrandt, M Korb, S Oßwald… - … A European Journal, 2016 - Wiley Online Library
Abstract Complexes [{Ru (CO) Cl (PiPr3) 2} 2 (μ‐2, 5‐(CH CH) 2‐cC4H2E](E= NR; R=
C6H4‐4‐NMe2 (10 a), C6H4‐4‐OMe (10 b), C6H4‐4‐Me (10 c), C6H5 (10 d), C6H4‐4 …

Rational Control of Conformational Distributions and Mixed‐Valence Characteristics in Diruthenium Complexes

JBG Gluyas, S Gückel, M Kaupp… - Chemistry–A European …, 2016 - Wiley Online Library
The electronic characteristics of mixed‐valence complexes are often inferred from the shape
of the inter‐valence charge transfer (IVCT) band, which usually falls in the near infrared …

Functionalised organometallic photoswitches containing dihydropyrene units

AA Gillespie, M Roemer, D Jago, AN Sobolev… - Dalton …, 2023 - pubs.rsc.org
Functionalising organic molecular photoswitches with metal complexes has been shown to
alter and enhance their switching states. These organometallic photoswitches provide a …

Bonding and electronic properties of linear diethynyl oligothienoacene-bridged diruthenium complexes and their oxidized forms

YP Ou, J Zhang, MX Zhang, F Zhang, D Kuang… - Inorganic …, 2017 - ACS Publications
A series of five diruthenium diethynyl complexes based on α, β-fused oligothienoacenes in
the core of the bridging ligands [{Ru (dppe) Cp*} 2 (μ-C C–L–C C)][dppe= 1, 2-bis …

Electronic properties of poly‐yne carbon chains and derivatives with transition metal end‐groups

F Gendron, T Groizard, B Le Guennic… - European Journal of …, 2020 - Wiley Online Library
During the last three decades, experimental chemists have forged a plethora of bimetallic
molecular wires in which two redox‐active metal termini are linked by a carbon‐rich bridge …

Notable differences between oxidized diruthenium complexes bridged by four isomeric diethynyl benzodithiophene ligands

YP Ou, J Zhang, F Zhang, D Kuang, F Hartl, L Rao… - Dalton …, 2016 - pubs.rsc.org
Four new diruthenium complexes [{(η5-C5Me5) Ru (dppe)} 2 (μ-CC–L–CC)] featuring
different bridging isomeric diethynyl benzodithiophenes viz. L= benzo [1, 2-b; 4, 5-b′] …

Synthesis and charge delocalization property of multimetallic molecular wires with diethynylthiophene bridges

K Sugimoto, H Idei, Y Tanaka, M Akita - Journal of Organometallic …, 2017 - Elsevier
Here we report properties of thiophene-rich, acetylide-type mono-, di-and tri-nuclear
ruthenium molecular wires 1–4, which are prepared by rationally designed coupling of …