Recent years have witnessed a resurgence of novel, efficient and practical protocols for
radical‐mediated cross‐coupling reactions involving N‐(acyloxy) phthalimides (NHPI esters) …

C− C bond forming reactions incarnate the core of organic synthesis because of their
fundamental applications to molecular diversity and complexity. In recent years, use of …

The area of transition‐metal‐catalyzed direct arylation through cleavage of C H bonds has
undergone rapid development in recent years, and is becoming an increasingly viable …

Aromatic substrates with oxygen‐and nitrogen‐containing substituents undergo oxidative
coupling with alkynes and alkenes under rhodium catalysis through regioselective C H …

This critical review examines transition metal-catalyzed decarboxylative couplings that have
emerged within recent years as a powerful strategy to form carbon–carbon or carbon …

Photochemistry has ushered in a new era in the development of chemistry, and photoredox
catalysis has become a hot topic, especially over the last five years, with the combination of …

In this Review, we summarize the current state of the art in late‐transition‐metal‐catalyzed
reactions of acyl fluorides, covering both their synthesis and further transformations. In …

Nickel catalysis for biaryl coupling reactions has received significant attention as a less
expensive and less toxic alternative to “standard” palladium catalysis. Here we describe …

Carboxylic acids and their derivatives are abundant and inexpensive organic and biomass‐
derived platform molecules, and their conversion into high‐value products represents an …

Abstract Synergistic Pd/Cu catalysis has been utilized in the Sonogashira reaction since
1975. However, this strategy has not received much attention from the organic chemist …