Oxo-centered trinuclear ruthenium acetates: Structure and applications

S Nikolaou, LGA do Nascimento… - Coordination Chemistry …, 2023 - Elsevier
Polynuclear μ-oxo complexes are commonly observed for second and third row transition
metals. This review is particularly interested in the μ 3-oxo-bridged ruthenium trinuclear …

Inorganic reaction mechanisms. A personal journey

CD Hubbard, D Chatterjee, M Oszajca, J Polaczek… - Dalton …, 2020 - pubs.rsc.org
This review covers highlights of the work performed in the van Eldik group on inorganic
reaction mechanisms over the past two decades in the form of a personal journey. Topics …

Investigation of a novel trinuclear μ-oxo ruthenium complex as a potential nitric oxide releaser for biological purposes

N Cacita, B Possato, CFN da Silva, M Paulo… - Inorganica Chimica …, 2015 - Elsevier
The chemical properties of the trinuclear ruthenium complex [Ru 3 O (CH 3 COO) 6 (3-pic) 2
(NO)] PF 6 (1, were 3-pic= 3-picoline or 3-methylpyridine), its photochemical behavior and …

SNS versus SNN Pincer Ligands: Electrochemical Studies and Their Palladium (II) Complexes as Electro‐Catalyst for Proton Reduction

MAW Lawrence, WH Mulder - ChemistrySelect, 2018 - Wiley Online Library
Electrochemical measurements on pincer ligands bis‐N‐(2, 5‐dimethoxyphenyl) pyridine‐2,
6‐dicarbothioamide (pdcta) and 6‐(4, 7‐dimethoxy‐2‐benzothiazolyl)‐N‐(2, 5 …

Assessing the stability of the Co (I) species of two mononuclear dichlorocobalt compounds bearing 2, 2′-bipyridine and trans-2-(2′-quiolyl) methylene-3 …

MAW Lawrence, AA Holder - Inorganica Chimica Acta, 2016 - Elsevier
The Co (I) species resulting from the reduction of two mononuclear species [CoL n Cl
2](where L= 2, 2′-bipyridine (bpy) and n= 2, or L= trans-2-(2′-quiolyl) methylene-3 …

Water‐Soluble μ‐oxo triruthenium Compound of Biological Interest: H‐Bonds Network and Interaction with HSA

BFA Pinheiro, NC Fernandes… - European Journal of …, 2024 - Wiley Online Library
The water‐soluble compound [Ru3O (CH3COO) 6 (4‐ampy) 3] Cl (1, 4‐ampy= 4‐
aminopyridine) was evaluated in terms of its biologically relevant properties. Compound 1 …

Assessment of two cobalt (II) complexes with pincer ligands for the electrocatalytic hydrogen evolution reaction. A comparison of the SNS vs ONS coordination

MAW Lawrence, WH Mulder, MJ Celestine… - Inorganica Chimica …, 2020 - Elsevier
Abstract Bis-N-(2, 5-dimethoxyphenyl) pyridine-2, 6-dicarbothioamide (pdcta) and N-(2, 5-
dimethoxyphenyl)-6-[(2, 5-dimethoxyphenyl) carbamothioyl] pyridine-2-carboxamide (pcta) …

Synthesis, X-ray crystallographic, electrochemical, and spectroscopic studies of Bis-(1, 10-phenanthroline)(2, 2′-bipyridine) cobalt (III) Hexafluorophosphate

MAW Lawrence, CD McMillen, RK Gurung… - Journal of Chemical …, 2015 - Springer
The synthesis, X-ray crystallographic, electrochemical, and spectroscopic studies of bis-(1,
10-phenanthroline)(2, 2′-bipyridine) cobalt (III) hexafluorophosphate with acetone solvent …

Basic coordination chemistry of ruthenium

MAW Lawrence, JL Bullock… - Ruthenium complexes …, 2018 - Wiley Online Library
This introductory chapter outlines the basic coordination chemistry of ruthenium in its known
oxidation states and attempts to relate selected applications to each oxidation state …

Kinetics and Mechanism of the Reduction of mer‐Tris‐picolinatoruthenium(III) by L‐Ascorbic Acid

A Katafias, O Impert, P Kita, J Fenska… - European Journal of …, 2014 - Wiley Online Library
The kinetics of reduction of the mer‐[RuIII (pic) 3] complex (pic–= picolinato) by ascorbic acid
(AscH2) leading to formation of a red ruthenium (II) species have been studied …