Biological applications of supramolecular assemblies designed for excitation energy transfer

HQ Peng, LY Niu, YZ Chen, LZ Wu, CH Tung… - Chemical …, 2015 - ACS Publications
Absorption of light by a molecule (donor, D) generates an excited state, which may
subsequently transfer the excitation to another chromophore (acceptor, A) in the vicinity …

[HTML][HTML] The effects of layered nanoparticles and their properties on the molecular aggregation of organic dyes

J Bujdák - Journal of Photochemistry and Photobiology C …, 2018 - Elsevier
The phenomenon of metachromasia, which is related to molecular aggregation, leads to
significant changes in the photophysical properties of dyes. This review summarizes existing …

Size-matching effect on inorganic nanosheets: control of distance, alignment, and orientation of molecular adsorption as a bottom-up methodology for nanomaterials

S Takagi, T Shimada, Y Ishida, T Fujimura, D Masui… - Langmuir, 2013 - ACS Publications
We have been investigating complexes composed of nanolayered materials with anionic
charges such as clay nanosheets and dye molecules such as cationic porphyrins. It was …

The mechanism of the porphyrin spectral shift on inorganic nanosheets: the molecular flattening induced by the strong host–guest interaction due to the “size-matching …

Y Ishida, D Masui, T Shimada… - The Journal of …, 2012 - ACS Publications
The mechanism inducing the unique absorption spectral shifts of porphyrin molecules upon
adsorption on the clay surface was experimentally confirmed to be the flattening of the meso …

“Surface-fixation induced emission” of porphyrazine dye by a complexation with inorganic nanosheets

Y Ishida, T Shimada, S Takagi - The Journal of Physical Chemistry …, 2014 - ACS Publications
This paper proposes a unique phenomenon of the strong enhancement in the fluorescence
quantum yield (φf) and the excited lifetime (τ) of tetra-cationic porphyrazine dye (Pz) upon a …

[HTML][HTML] Designed functions of oxide/hydroxide nanosheets via elemental replacement/doping

K Saito, M Morita, T Okada, M Ogawa - Chemical Society Reviews, 2024 - pubs.rsc.org
Partial replacement of one structural element in a solid with another of a similar size was
conducted to impart functionality to the solids and modify their properties. This phenomenon …

Manipulation of precise molecular arrangements and their photochemical properties on inorganic surfaces via multiple electrostatic interactions

Y Ishida - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
Multiple (or multivalent) interaction is the key in many biological systems. One of the most
important (photo-) chemical reactions, photosynthesis, is driven by regularly aligned …

Hydrophilicity Control of Visible‐Light Hydrogen Evolution and Dynamics of the Charge‐Separated State in Dye/TiO2/Pt Hybrid Systems

WS Han, KR Wee, HY Kim, C Pac… - … A European Journal, 2012 - Wiley Online Library
Visible‐light‐driven H2 evolution based on Dye/TiO2/Pt hybrid photocatalysts was
investigated for a series of (E)‐3‐(5′‐{4‐[bis (4‐R1‐phenyl) amino] phenyl}‐4, 4′‐(R2) 2 …

Adsorption-induced dye stability of cationic dyes on clay nanosheets

AP Teepakakorn, S Bureekaew, M Ogawa - Langmuir, 2018 - ACS Publications
Rhodamine 6G (R6G) was adsorbed on smectite clays, a natural montmorillonite, a synthetic
saponite, and synthetic hectorites, and the decolorization of the dyes upon visible light …

Regulation of the collisional self-quenching of fluorescence in clay/porphyrin complex by strong host–guest interaction

Y Ishida, T Shimada, H Tachibana… - The Journal of …, 2012 - ACS Publications
This paper proposes a novel methodology to improve noncollisional photochemical
reactions such as Förster resonance energy transfer on solid surfaces. Since an excited …