Deciphering the chameleonic chemistry of allenols: breaking the taboo of a onetime esoteric functionality
JM Alonso, P Almendros - Chemical Reviews, 2021 - ACS Publications
The allene functionality has participated in one of the most exciting voyages in organic
chemistry, from chemical curiosities to a recurring building block in modern organic …
chemistry, from chemical curiosities to a recurring building block in modern organic …
Recent advances in the metal-catalyzed asymmetric synthesis of chiral allenes
W Xiao, J Wu - Organic Chemistry Frontiers, 2022 - pubs.rsc.org
Chiral allenes, which exist widely in natural products, bioactive pharmaceuticals, and
advanced functional materials, have received considerable attention from chemists. They …
advanced functional materials, have received considerable attention from chemists. They …
Catalytic enantioconvergent allenylation of aldehydes with propargyl halides
FH Zhang, X Guo, X Zeng… - Angewandte Chemie …, 2022 - Wiley Online Library
Abstract α‐Allenol is a versatile synthon in organic synthesis. The catalytic asymmetric
synthesis of α‐allenols from readily available starting materials remains a prominent …
synthesis of α‐allenols from readily available starting materials remains a prominent …
Distinctive mechanistic scenarios and substituent effects of gold (I) versus copper (I) catalysis for hydroacylation of terminal alkynes with glyoxal derivatives
XA Yuan, D Li, S Wang, YY Jiang, P Liu… - The Journal of Organic …, 2022 - ACS Publications
Density functional theory (DFT) calculations have been conducted to study the mechanisms,
substituent effects, and the role of bases in Au-and Cu-catalyzed hydroacylation of terminal …
substituent effects, and the role of bases in Au-and Cu-catalyzed hydroacylation of terminal …
Indium-mediated annulation of 2-azidoaryl aldehydes with propargyl bromides to [1, 2, 3] triazolo [1, 5-a] quinolines
X Zhang, J Yang, N Xiong, Z Han, X Duan… - Organic & Biomolecular …, 2021 - pubs.rsc.org
An efficient indium-mediated cascade annulation reaction of 2-azidoaryl aldehydes with
propargyl bromides is reported. The aromatic 5/6/6-fused heterocycles,[1, 2, 3] triazolo [1, 5 …
propargyl bromides is reported. The aromatic 5/6/6-fused heterocycles,[1, 2, 3] triazolo [1, 5 …
DFT study on the E-stereoselective reductive A 3-coupling reaction of terminal alkynes with aldehydes and 3-pyrroline
Y Yao, X Zhang, S Ma - Organic Chemistry Frontiers, 2020 - pubs.rsc.org
The mechanism of the Cu (I)-catalyzed reductive A3-coupling reaction of terminal alkynes
with aldehydes and 3-pyrroline for the synthesis of E-allylic amines has been studied by DFT …
with aldehydes and 3-pyrroline for the synthesis of E-allylic amines has been studied by DFT …
Differences in mechanisms between divalent and univalent copper complexes-catalyzed hydroacylation of terminal alkyne with aldehyde and amine
XA Yuan, R Tao, D Li, X Zhang, YY Jiang, P Liu, S Bi - Molecular Catalysis, 2024 - Elsevier
DFT calculations are carried out to investigate the hydroacylation mechanism based on
copper-catalyzed A 3-coupling tandem reaction of terminal alkynes, aldehydes and amines …
copper-catalyzed A 3-coupling tandem reaction of terminal alkynes, aldehydes and amines …
Allenation of Terminal Alkynes for Allene Synthesis
X Zhang, S Ma - Homologation Reactions: Reagents …, 2023 - Wiley Online Library
Allenes have been demonstrated to be synthetically versatile building blocks toward
complex molecular targets in natural product synthesis, pharmaceutical chemistry, and …
complex molecular targets in natural product synthesis, pharmaceutical chemistry, and …