The polarizability model for ferroelectricity in perovskite oxides

A Bussmann-Holder - Journal of Physics: Condensed Matter, 2012 - iopscience.iop.org
This article reviews the polarizability model and its applications to ferroelectric perovskite
oxides. The motivation for the introduction of the model is discussed and nonlinear oxygen …

NMR Evidence for the Coexistence of Order-Disorder and Displacive Components<? format?> in Barium Titanate

B Zalar, VV Laguta, R Blinc - Physical review letters, 2003 - APS
A quadrupole coupling induced T 47 i and T 49 i satellite background which transforms into
well-defined satellite lines below T c in the ferroelectric phase has been observed in the …

Coexistence of the Phonon and Relaxation Soft Modes in the Terahertz Dielectric Response <?format ?>of Tetragonal

J Hlinka, T Ostapchuk, D Nuzhnyy, J Petzelt, P Kuzel… - Physical Review Letters, 2008 - APS
The dielectric response to infrared waves polarized along the tetragonal axis of a
ferroelectric single-domain crystal of BaTiO 3 was determined by time-domain THz …

Off-center model of barium titanate

R Pirc, R Blinc - Physical Review B—Condensed Matter and Materials …, 2004 - APS
It has recently been shown by NMR techniques that in the high-temperature cubic phase of
BaTiO 3 the Ti ions are not confined to the high-symmetry cubic sites, but rather occupy one …

Precursor effects, broken local symmetry, and coexistence of order-disorder and displacive dynamics in perovskite ferroelectrics

A Bussmann-Holder, H Beige, G Völkel - Physical Review B—Condensed …, 2009 - APS
The dynamical properties of ferroelectric perovskites have typically been classified as being
either of order-disorder or displacive type. Here we show that this simple scheme is not …

Disorder origin of Raman scattering in perovskite single crystals

M Menahem, N Benshalom, M Asher, S Aharon… - Physical Review …, 2023 - APS
The anharmonic lattice dynamics of oxide and halide perovskites play a crucial role in their
mechanical and optical properties. Raman spectroscopy is one of the key methods used to …

In situ Raman spectroscopy of A-site doped barium titanate

UM Pasha, H Zheng, OP Thakur, A Feteira… - Applied physics …, 2007 - pubs.aip.org
Raman spectroscopy has been used to study the ferroelectric tetragonal to paraelectric
cubic phase transition T c in undoped Ba Ti O 3 (BT) and (Ba 0.92 A 0.08) Ti O 3 [where A …

Lattice dynamics in single crystals: A Raman study

DA Tenne, A Soukiassian, XX Xi, H Choosuwan… - Physical Review B …, 2004 - APS
The lattice dynamical properties of Ba x Sr 1− x TiO 3 single crystals with x= 0.05, 0.1, 0.2,
0.35, and 0.5 have been studied by Raman spectroscopy in the temperature range 5–300 K …

Above-room-temperature molecular ferroelectric and fast switchable dielectric of diisopropylammonium perchlorate

K Gao, M Gu, X Qiu, XN Ying, HY Ye… - Journal of Materials …, 2014 - pubs.rsc.org
The transition temperatures of molecular ferroelectrics are usually lower than those of
inorganic ferroelectrics due to weaker electron–electron and electron–phonon interactions …

Picosecond View of Microscopic-Scale Polarization Clusters in Paraelectric

RZ Tai, K Namikawa, A Sawada, M Kishimoto… - Physical review …, 2004 - APS
The polarization clusters existing in both the ferroelectric and the paraelectric phase of B a T
i O 3 are directly observed and characterized for the first time by a picosecond soft x-ray …