Metal–organic framework-based hierarchically porous materials: synthesis and applications

G Cai, P Yan, L Zhang, HC Zhou, HL Jiang - Chemical Reviews, 2021 - ACS Publications
Metal–organic frameworks (MOFs) have been widely recognized as one of the most
fascinating classes of materials from science and engineering perspectives, benefiting from …

Metal–organic frameworks based on multicarboxylate linkers

H Ghasempour, KY Wang, JA Powell… - Coordination Chemistry …, 2021 - Elsevier
When designing metal–organic frameworks (MOFs), linker design is one of the most
important factors in constructing a wide variety of structures. Judicious choice of linker size …

Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Z Chen, SL Hanna, LR Redfern, D Alezi… - Coordination Chemistry …, 2019 - Elsevier
In the past two decades, reticular chemistry has developed into a powerful tool for the design
and synthesis of porous, crystalline framework materials. The discovery of the first …

Node-accessible zirconium MOFs

Z Lu, J Liu, X Zhang, Y Liao, R Wang… - Journal of the …, 2020 - ACS Publications
High-stability, zirconium-based metal–organic frameworks are attractive as heterogeneous
catalysts and as model supports for uniform arrays of subsequently constructed …

[HTML][HTML] Mixed component metal-organic frameworks: Heterogeneity and complexity at the service of application performances

M Viciano-Chumillas, X Liu, A Leyva-Pérez… - Coordination Chemistry …, 2022 - Elsevier
The synthesis of mixed-component metal-organic frameworks (MOFs)–including multivariate
MOFs (MTV-MOFs), multicomponent MOFs, mixed-metals MOFs and mixed-ligands and …

[HTML][HTML] Hierarchically engineered mesoporous metal-organic frameworks toward cell-free immobilized enzyme systems

P Li, Q Chen, TC Wang, NA Vermeulen, BL Mehdi… - Chem, 2018 - cell.com
Highly efficient cell-free enzymatic systems are typically difficult to achieve in traditional
immobilized enzyme systems because of the lack of optimal spatial control of enzyme …

[HTML][HTML] Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers

H Wang, X Dong, J Lin, SJ Teat, S Jensen… - Nature …, 2018 - nature.com
As an alternative technology to energy intensive distillations, adsorptive separation by
porous solids offers lower energy cost and higher efficiency. Herein we report a topology …

Structural diversity of zirconium metal–organic frameworks and effect on adsorption of toxic chemicals

Y Chen, X Zhang, MR Mian, FA Son… - Journal of the …, 2020 - ACS Publications
While linkers with various conformations pose challenges in the design and prediction of
metal–organic framework (MOF) structures, they ultimately provide great opportunities for …

[PDF][PDF] Hierarchically porous metal–organic frameworks: synthetic strategies and applications

L Feng, KY Wang, XL Lv, TH Yan… - National Science …, 2020 - academic.oup.com
Despite numerous advantages, applications of conventional microporous metal–organic
frameworks (MOFs) are hampered by their limited pore sizes, such as in heterogeneous …

Structural defects in metal–organic frameworks (MOFs): Formation, detection and control towards practices of interests

J Ren, M Ledwaba, NM Musyoka, HW Langmi… - Coordination Chemistry …, 2017 - Elsevier
Research on metal–organic framework (MOF) materials has gathered increasing interest
starting from the early excitement as porous materials for gas storage down to various novel …