Synthesis of Nickel (I)–Bromide Complexes via Oxidation and Ligand Displacement: Evaluation of Ligand Effects on Speciation and Reactivity

SH Newman-Stonebraker, TJ Raab… - Journal of the …, 2023 - ACS Publications
Nickel's+ 1 oxidation state has received much interest due to its varied and often enigmatic
behavior in increasingly popular catalytic methods. In part, the lack of understanding about …

Mechanism of Ni-Catalyzed Photochemical Halogen Atom-Mediated C(sp3)–H Arylation

AQ Cusumano, BC Chaffin… - Journal of the American …, 2024 - ACS Publications
Within the context of Ni photoredox catalysis, halogen atom photoelimination from Ni has
emerged as a fruitful strategy for enabling hydrogen atom transfer (HAT)-mediated C (sp3) …

A C-to-O atom-swapping reaction sequence enabled by Ni-catalyzed decarbonylation of lactones

QH Luu, J Li - Chemical Science, 2022 - pubs.rsc.org
Advances in site-selective functionalization reactions have enabled single atom changes on
the periphery of a complex molecule, but reaction manifolds that enable such changes on …

Revised Mechanism of C(sp3)–C(sp3) Reductive Elimination from Ni(II) with the Assistance of a Z-Type Metalloligand

T Zhang, K Zhong, ZK Lin, L Niu, ZQ Li… - Journal of the …, 2023 - ACS Publications
Reductive elimination is a key step in Ni-catalyzed cross-couplings. Compared with
processes that proceed from Ni (III) or Ni (IV) intermediates, C (sp3)–C (sp3) reductive …

Benzylic C− H Radical Sulfation by Persulfates

Z Xia, Z Ye, T Deng, Z Tan, C Song… - Angewandte Chemie …, 2024 - Wiley Online Library
Sulfation is a highly valuable pathological and physiological process, yet it is often
underappreciated considering the rather difficult accessibility of organosulfates. O …

Ni-catalyzed ligand-controlled selective 5-exo and 6-endo cyclization/cross-couplings involving an unusual 1, 2-aryl migration

M Yang, N Liu, Z Zhang, YB She, YF Yang - ACS Catalysis, 2022 - ACS Publications
Nickel-catalyzed ligand-controlled reductive dicarbofunctionalization of alkenes provides a
regiodivergent synthetic strategy for constructing five-and six-membered benzo-fused …

High Selectivity in Csp2–Csp2 versus Csp3–O Reductive Elimination from Cycloplatinated (IV) Complexes

MD Aseman, S Kiyavash - Inorganic Chemistry, 2024 - ACS Publications
High Selectivity in Csp2–Csp2 versus Csp3–O Reductive Elimination from Cycloplatinated(IV)
Complexes | Inorganic Chemistry Recently Viewedclose modal Pair your accounts. Export …