Dearomatization reactions provide a synthetic connection between readily available, simple
aromatic starting materials and more saturated intermediates of greater molecular …

The chiral oxazoline motif is present in many ligands that have been extensively applied in a
series of important metal-catalyzed enantioselective reactions. This Review aims to provide …

Arene hydrogenation provides direct access to saturated carbo‐and heterocycles and thus
its strategic application may be used to shorten synthetic routes. This powerful …

Bidentate P, N ligands, integrating phosphine and nitrogen donors, are highlighted for their
versatile characteristics, offering both electronic and steric tunability. Their hemilabile nature …

Visible-light-driven organic photochemical reactions have attracted substantial attention
from the synthetic community. Typically, catalytic quantities of photosensitizers, such as …

Arene dearomatization is a straightforward method for converting an aromatic feedstock into
functionalized carbocycles. Enantioselective dearomatizations of chemically inert arenes …

Nonactivated arenes, such as benzene derivatives, are chemically inert due to their intrinsic
aromaticity and low polarity. The catalytic asymmetric dearomatization (CADA, coined by …

We report that the dearomative [4+ 2] cycloaddition between 1, 2-dihydro-1, 2, 4, 5-tetrazine-
3, 6-diones (TETRADs) and benzenes, naphthalenes, or N-heteroaromatic compounds …

Oxa-and azabicyclic alkenes can be readily activated by transition-metal complexes with
facial selectivity, because of the intrinsic reactivity of strained bicyclic structures …

The dearomatization of aromatic compounds is an important synthetic strategy used in
accessing complex three‐dimensional structures from simple aromatic precursors. This …