Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Conspectus The oxindole scaffold is a privileged structural motif that is found in a variety of
bioactive targets and natural products. Moreover, derivatives of the oxindole structure are …

An unprecedented asymmetric acyl-carbamoylation of pendant alkenes tethered on aryl
carbamic chlorides with both aliphatic and aromatic aldehydes has been developed via the …

In contrast to the extensive but non-recyclable use of tetraalkoxydiboron (4) compounds as
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …

Herein, we report a nickel-catalyzed reductive cross-coupling reaction of easily accessible 3-
butenyl carbamoyl chloride with primary alkyl iodide to access the chiral α-alkylated …

Catalytic asymmetric C–C bond formation with alkylcopper intermediates as carbon
nucleophiles is now textbook chemistry. Related chemistry with boron and silicon …

Natural goods, medications, and pharmaceutically active substances all contain substituted
oxindoles. Generally, the C-3 stereocenter of the substituents of oxindoles and their absolute …

A mild visible-light-induced Pd-catalyzed one-pot three-component alkyl-carbamoylation
and cyanation of alkenes was developed. This general transformation, which proceeds via …