The comparison between single atom catalysis and surface organometallic catalysis

MK Samantaray, V D'Elia, E Pump, L Falivene… - Chemical …, 2019 - ACS Publications
Single atom catalysis (SAC) is a recent discipline of heterogeneous catalysis for which a
single atom on a surface is able to carry out various catalytic reactions. A kind of revolution …

Advances and challenges of methanol-tolerant oxygen reduction reaction electrocatalysts for the direct methanol fuel cell

MAU Din, M Idrees, S Jamil, S Irfan, G Nazir… - Journal of Energy …, 2023 - Elsevier
Methanol cross-over effects from the anode to the cathode are important parameters for
reducing catalytic performance in direct methanol fuel cells. A promising candidate catalyst …

Theory-guided materials design: two-dimensional MXenes in electro-and photocatalysis

AD Handoko, SN Steinmann, ZW Seh - Nanoscale Horizons, 2019 - pubs.rsc.org
Two-dimensional transition metal carbides and nitrides (MXenes) have made a significant
impact on sustainable energy research in the fields of energy storage and conversion …

Exchange current density as an effective descriptor of poisoning of active sites in platinum group metal-free electrocatalysts for oxygen reduction reaction

VCA Ficca, C Santoro, E Placidi, F Arciprete… - ACS …, 2023 - ACS Publications
The oxygen reduction reaction (ORR) is of primary importance for the direct and clean
conversion of energy in fuel cells, necessarily requiring an electrocatalyst to be exploited. At …

Carbon monoxide poisoning resistance and structural stability of single atom alloys

MT Darby, ECH Sykes, A Michaelides, M Stamatakis - Topics in catalysis, 2018 - Springer
Platinum group metals (PGMs) serve as highly active catalysts in a variety of heterogeneous
chemical processes. Unfortunately, their high activity is accompanied by a high affinity for …

Skeletal Octahedral Nanoframe with Cartesian Coordinates via Geometrically Precise Nanoscale Phase Segregation in a Pt@Ni Core–Shell Nanocrystal

A Oh, H Baik, DS Choi, JY Cheon, B Kim, H Kim… - ACS …, 2015 - ACS Publications
Catalytic properties of nanoparticles can be significantly enhanced by controlling nanoscale
alloying and its structure. In this work, by using a facet-controlled Pt@ Ni core–shell …

Effect of anode material on electrochemical oxidation of low molecular weight alcohols—A review

M Wala, W Simka - Molecules, 2021 - mdpi.com
The growing climate crisis inspires one of the greatest challenges of the 21st century—
developing novel power sources. One of the concepts that offer clean, non-fossil electricity …

Template‐guided regioselective encaging of platinum single atoms into Y zeolite: Enhanced selectivity in semihydrogenation and resistance to poisoning

Q Chen, P Peng, G Yang, Y Li, M Han… - Angewandte Chemie …, 2022 - Wiley Online Library
It is challenging to establish single metal atoms with a uniform coordination environment at
targeted sites of a zeolite. In this study, single platinum atoms were selectively encaged in …

Biocatalytic micromixer coated with enzyme-MOF thin film for CO2 conversion to formic acid

M Chai, SR Bazaz, R Daiyan, A Razmjou… - Chemical Engineering …, 2021 - Elsevier
In this study, a novel micromixer with a 3D helical, threaded channel was fabricated via 3D
printing. The micromixer can enhance the mass transfer of reactants and product in an …

Design strategies of Pt-based electrocatalysts and tolerance strategies in fuel cells: a review

W Luo, Y Jiang, M Wang, D Lu, X Sun, H Zhang - RSC advances, 2023 - pubs.rsc.org
As highly efficient conversion devices, proton-exchange-membrane fuel cells (PEMFCs) can
directly convert chemical energy to electrical energy with high efficiencies and lower or even …