Organic photoredox catalysis

NA Romero, DA Nicewicz - Chemical reviews, 2016 - ACS Publications
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …

Bio-sourced monomers and cationic photopolymerization–The green combination towards eco-friendly and non-toxic materials

L Pierau, C Elian, J Akimoto, Y Ito, S Caillol… - Progress in Polymer …, 2022 - Elsevier
Cationic photopolymerization is amongst the greenest processes used to obtain polymers
since light is abundant, inexpensive and allows for rapid and waste-less curing at room …

Shining a light on an adaptable photoinitiator: advances in photopolymerizations initiated by thioxanthones

S Dadashi-Silab, C Aydogan, Y Yagci - Polymer Chemistry, 2015 - pubs.rsc.org
Photochemistry plays a central role in synthetic polymer research. Aromatic ketones,
examples of which include benzophenone, thioxanthone, camphorquinone, among others …

From light to structure: photo initiators for radical two‐photon polymerization

T Wloka, M Gottschaldt… - Chemistry–A European …, 2022 - Wiley Online Library
Abstract Two‐photon polymerization (2PP) represents a powerful technique for the
fabrication of precise three‐dimensional structures on a micro‐and nanometer scale for …

A straightforward synthesis and structure–activity relationship of highly efficient initiators for two-photon polymerization

Z Li, N Pucher, K Cicha, J Torgersen, SC Ligon… - …, 2013 - ACS Publications
The development of practical two-photon absorption photoinitiators (TPA PIs) has been slow
due to their complicated syntheses often reliant on expensive catalysts. These shortcomings …

Bicarbazole-based oxime esters as novel efficient photoinitiators for photopolymerization under UV-Vis LEDs

R Zhou, H Pan, D Wan, JP Malval, M Jin - Progress in Organic Coatings, 2021 - Elsevier
Five novel oxime ester type photoinitiators based on the bicarbazole structure were
designed and synthesized to extend the absorption wavelength range of photoinitiators to …

Chemical regulation of fluorescence lifetime

J Dai, X Zhang - Chemical & Biomedical Imaging, 2023 - ACS Publications
Fluorescence lifetime has significant applications in the field of fluorescence microscopy.
Effective modulation of fluorescence lifetime can be achieved by controlling the radiative …

Wavelength-dependent, large-amplitude photoinitiating reactivity within a carbazole-coumarin fused oxime esters series

R Zhou, X Sun, R Mhanna, JP Malval… - ACS Applied Polymer …, 2020 - ACS Publications
In this current contribution, we provide a detailed investigation into the photochemistry and
the free radical photoinitiating reactivity of LED light-sensitive photoinitiators (PIs). This …

Ultrafast, high-resolution and large-size three-dimensional structure manufacturing through high-efficiency two-photon polymerization initiators

S Zhang, S Li, X Wan, J Ma, N Li, J Li, Q Yin - Additive Manufacturing, 2021 - Elsevier
In this article, we report the synthesis of a series of π-expanded benzophenone-based
photoinitiators for additive manufacturing based on two-photon polymerization, and detailed …

A two-photon active chevron-shaped type I photoinitiator designed for 3D stereolithography

R Zhou, JP Malval, M Jin, A Spangenberg… - Chemical …, 2019 - pubs.rsc.org
We present herein the properties of a highly reactive type I photoinitiator with significant 2PA
cross-sections (δ720nm∼ 90 GM). We demonstrate that this new type of photocleavable …