The story of the little blue box: a tribute to Siegfried Hünig

XY Chen, H Chen… - Angewandte Chemie …, 2023 - Wiley Online Library
The tetracationic cyclophane, cyclobis (paraquat‐p‐phenylene), also known as the little blue
box, constitutes a modular receptor that has facilitated the discovery of many host–guest …

Supramolecular and molecular capsules, cages and containers

CJT Cox, J Hale, P Molinska, JEM Lewis - Chemical Society Reviews, 2024 - pubs.rsc.org
Stemming from early seminal notions of molecular recognition and encapsulation, three-
dimensional, cavity-containing capsular compounds and assemblies have attracted intense …

Exciplex Emission and Förster Resonance Energy Transfer in Polycyclic Aromatic Hydrocarbon-Based Bischromophoric Cyclophanes and Homo [2] catenanes

A Garci, S Abid, AHG David, LO Jones… - Journal of the …, 2023 - ACS Publications
Energy transfer and exciplex emission are not only crucial photophysical processes in many
living organisms but also important for the development of smart photonic materials. We …

Charge-assisted hydrogen bonding in a bicyclic amide cage: an effective approach to anion recognition and catalysis in water

C Xu, QG Tran, D Liu, C Zhai, L Wojtas, W Liu - Chemical Science, 2024 - pubs.rsc.org
Hydrogen bonding is prevalent in biological systems, dictating a myriad of life-sustaining
functions in aqueous environments. Leveraging hydrogen bonding for molecular recognition …

Alkoxy-substituted quadrupolar fluorescent dyes

Y Feng, PJ Das, RM Young, PJ Brown… - Journal of the …, 2022 - ACS Publications
Polar and polarizable π-conjugated organic molecules containing push–pull chromophores
have been investigated extensively in the past. Identifying unique backbones and building …

A Fluorescent Cage for Supramolecular Sensing of 3‐Nitrotyrosine in Human Blood Serum

LA Pérez‐Márquez, MD Perretti… - Angewandte Chemie …, 2022 - Wiley Online Library
Nitrotyrosine (NT) is generated by the action of peroxynitrite and other reactive nitrogen
species (RNS), and as a consequence it is accumulated in inflammation‐associated …

Development of porphyrin-based fluorescent sensors and sensor arrays for saccharide recognition

Y Ding, J Wang, R Wang, Y Xie - Chinese Chemical Letters, 2024 - Elsevier
Saccharide sensing is a very meaningful research topic as saccharides are involved in
many biological activities. However, it is challenging to design molecular sensors for …

From small changes to big gains: pyridinium-based tetralactam macrocycle for enhanced sugar recognition in water

C Zhai, EC Zulueta, A Mariscal, C Xu, Y Cui… - Chemical …, 2024 - pubs.rsc.org
The complex distribution of functional groups in carbohydrates, coupled with their strong
solvation in water, makes them challenging targets for synthetic receptors. Despite extensive …

Stimuli‐Mediated Structural Interchange Between Pd6 and Pd12 Architectures: Selective Recognition of E‐Stilbene by the Pd6 Architecture and its Photoprotection

M Aggarwal, R Banerjee, N Hickey… - Angewandte Chemie …, 2024 - Wiley Online Library
The dynamic behaviour of metal‐ligand bonding cultivates stimuli‐mediated structural
transformations in self‐assembled molecular architectures. The propensity of synthetically …

Precise Recognition in Water by an Endo‐Functionalized Cavity: Tuning the Complementarity of Binding Sites

YF Wang, SM Wang, X Zhang, H Nian… - Angewandte Chemie …, 2023 - Wiley Online Library
Precise binding towards structurally similar substrates is a common feature of biomolecular
recognition. However, achieving such selectivity—especially in distinguishing subtle …