Persistent and stable organic radicals: Design, synthesis, and applications

ZX Chen, Y Li, F Huang - Chem, 2021 - cell.com
Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

Efficient and air-stable n-type doping in organic semiconductors

D Yuan, W Liu, X Zhu - Chemical Society Reviews, 2023 - pubs.rsc.org
Chemical doping of organic semiconductors (OSCs) enables feasible tuning of carrier
concentration, charge mobility, and energy levels, which is critical for the applications of …

Exceptional Electron-Rich Heteroaromatic Pentacycle for Ultralow Band Gap Conjugated Polymers and Photothermal Therapy

CL Anderson, T Zhang, M Qi, Z Chen… - Journal of the …, 2023 - ACS Publications
Stable redox-active conjugated molecules with exceptional electron-donating abilities are
key components for the design and synthesis of ultralow band gap conjugated polymers …

Evolution of the electronic structure in open-shell donor-acceptor organic semiconductors

Z Chen, W Li, MA Sabuj, Y Li, W Zhu, M Zeng… - Nature …, 2021 - nature.com
Most organic semiconductors have closed-shell electronic structures, however, studies have
revealed open-shell character emanating from design paradigms such as narrowing the …

Red edge effect and chromoselective photocatalysis with amorphous covalent triazine-based frameworks

Y Zou, S Abednatanzi… - Nature …, 2022 - nature.com
Chromoselective photocatalysis offers an intriguing opportunity to enable a specific reaction
pathway out of a potentially possible multiplicity for a given substrate by using a sensitizer …

Organic radicals stabilization above 300° C in Eu-based coordination polymers for solar steam generation

X Ye, LH Chung, K Li, S Zheng, YL Wong… - Nature …, 2022 - nature.com
Organic radicals feature unpaired electrons, and these compounds may have applications in
biomedical technology and as materials for solar energy conversion. However, unpaired …

Diradical‐Featured Organic Small‐Molecule Photothermal Material with High‐Spin State in Dimers for Ultra‐Broadband Solar Energy Harvesting

J Sun, E Zhao, J Liang, H Li, S Zhao… - Advanced …, 2022 - Wiley Online Library
Organic materials with radical characteristics are gaining increasing attention, due to their
potential implications in highly efficient utilization of solar energy. Manipulating …

Electronic and Spintronic Open-Shell Macromolecules, Quo Vadis?

Y Tan, SN Hsu, H Tahir, L Dou, BM Savoie… - Journal of the …, 2022 - ACS Publications
Open-shell macromolecules (ie, polymers containing radical sites either along their
backbones or at the pendant sites of repeat units) have attracted significant attention owing …

Inhibitory effect and mechanism of l-ascorbic acid combined with tea polyphenols on coal spontaneous combustion

S Guo, Z Yan, S Yuan, W Geng - Energy, 2021 - Elsevier
The inhibitory effects of compound antioxidants (l-ascorbic acid (VC) and tea polyphenols
(TP)) on coal oxidation were studied. The characteristics of coal oxidation was investigated …

Broadband infrared photodetection using a narrow bandgap conjugated polymer

JH Vella, L Huang, N Eedugurala, KS Mayer, TN Ng… - Science …, 2021 - science.org
Photodetection spanning the short-, mid-, and long-wave infrared (SWIR-LWIR) underpins
modern science and technology. Devices using state-of-the-art narrow bandgap …