The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
Supramolecular assemblies on surfaces: nanopatterning, functionality, and reactivity
Understanding how molecules interact to form large-scale hierarchical structures on
surfaces holds promise for building designer nanoscale constructs with defined chemical …
surfaces holds promise for building designer nanoscale constructs with defined chemical …
Assembling molecular Sierpiński triangle fractals
J Shang, Y Wang, M Chen, J Dai, X Zhou, J Kuttner… - Nature …, 2015 - nature.com
Fractals, being “exactly the same at every scale or nearly the same at different scales” as
defined by Benoit B. Mandelbrot, are complicated yet fascinating patterns that are important …
defined by Benoit B. Mandelbrot, are complicated yet fascinating patterns that are important …
Halogen bonding in two‐dimensional crystal engineering
Halogen bonds, which provide an intermolecular interaction with moderate strength and
high directionality, have emerged as a promising tool in the repertoire of non‐covalent …
high directionality, have emerged as a promising tool in the repertoire of non‐covalent …
Halogen bonding in polymer science: from crystal engineering to functional supramolecular polymers and materials
Halogen bonding (XB) is commonly defined as a non-covalent bond where halogen atoms
(X= Cl, Br, I) function as electron acceptors. As an analogue of hydrogen bonding, halogen …
(X= Cl, Br, I) function as electron acceptors. As an analogue of hydrogen bonding, halogen …
Extended halogen bonding between fully fluorinated aromatic molecules
Halogen bonding is a noncovalent interaction where an electrophilic cap on a halogen
atom, the so-called σ-hole, attracts a nucleophilic site on an adjacent molecule. The …
atom, the so-called σ-hole, attracts a nucleophilic site on an adjacent molecule. The …
Engineering quantum states and electronic landscapes through surface molecular nanoarchitectures
Surfaces are at the frontier of every known solid. They provide versatile supports for
functional nanostructures and mediate essential physicochemical processes. Intimately …
functional nanostructures and mediate essential physicochemical processes. Intimately …
Halogen bonds in 2D supramolecular self-assembly of organic semiconductors
Weak interactions between bromine, sulphur, and hydrogen are shown to stabilize 2D
supramolecular monolayers at the liquid–solid interface. Three different thiophene-based …
supramolecular monolayers at the liquid–solid interface. Three different thiophene-based …
Bicomponent supramolecular architectures at the vacuum–solid interface
X Bouju, C Mattioli, G Franc, A Pujol… - Chemical …, 2017 - ACS Publications
This review aims at giving the readers the basic concepts needed to understand two-
dimensional bimolecular organizations at the vacuum–solid interface. The first part …
dimensional bimolecular organizations at the vacuum–solid interface. The first part …
[HTML][HTML] Surface-confined alternating copolymerization with molecular precision by stoichiometric control
L Xing, J Li, Y Bai, Y Lin, L Xiao, C Li, D Zhao… - Nature …, 2024 - nature.com
Keen desires for artificial mimicry of biological polymers and property improvement of
synthesized ones have triggered intensive explorations for sequence-controlled …
synthesized ones have triggered intensive explorations for sequence-controlled …