Conspectus Transition metal hydride catalyzed functionalization of remote and proximal
olefins has many advantages over conventional cross-coupling reactions. It avoids the …

Metal-catalyzed cross-electrophile couplings have become a valuable tool for carbon–
carbon bond formation. This minireview provides a comprehensive overview of the recent …

Polypyridine-ligated nickel complexes are widely used as privileged catalysts in a variety of
cross-coupling reactions. The rapid adoption of these complexes is tentatively attributed to …

Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

Cross-coupling reactions, which were discovered almost 50 years ago, are widely used in
both industry and academia. Even though cross-coupling reactions now represent mature …

The distant and selective activation of unreactive C–H and C–C bonds remains one of the
biggest challenges in organic chemistry. In recent years, the development of remote …

The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of
the most attractive strategies for increasing molecular complexity in synthetic organic …

A mild and regiodivergent aminoalkylation of unactivated alkyl halides is disclosed via a
dual photoredox/nickel catalysis. Bipyridyl-type ligands without an ortho-substituent control …

A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling
between an aryl halide and an alkyl halide has been developed in an undivided cell …

A nickel-catalyzed, multicomponent regio-and enantioselective coupling via sequential
hydroformylation and carbonylation from readily available starting materials has been …