Computational chemistry as a conceptual game changer: Understanding the role of London dispersion in hexaphenylethane derivatives (gomberg systems)

S Rösel, PR Schreiner - Israel Journal of Chemistry, 2022 - Wiley Online Library
The present personal perspective sheds light on the checkered history of hexaphenylethane
(HPE) and some of its key derivatives, including successes and failures in interpreting …

Single crystal investigation, Hirshfeld surface and interaction energy framework analyses of structure-directing interactions within two isomorphous Schiff's base …

A Dutta, S Mondal, PK Singh, B Ray - Journal of Molecular Structure, 2022 - Elsevier
The two new isomorphous Schiff's base multicomponent salts, 1 and 2, have been
synthesized using solvent assisted grinding (SAG) methodology and are characterized …

Experimental and theoretical insights into the formation of weak hydrogen bonds and H⋯ H bonding interactions in the solid-state structure of two eucalyptol …

CE Galvez, OE Piro, GA Echeverría… - New Journal of …, 2022 - pubs.rsc.org
Two eucalyptol derivatives, namely 1, 3, 3-trimethyl-2-oxabicycle [2.2. 2] oct-5-yl acetate (4)
and 1, 3, 3-trimethyl-2-oxabicycle [2.2. 2] oct-5, 8-yl acetate (6) have been synthesized and …

Low-Dimensional Architectures in Isomeric cis-PtCl2{Ph2PCH2N(Ar)CH2PPh2} Complexes Using Regioselective-N(Aryl)-Group Manipulation

P De'Ath, MRJ Elsegood, NM Sanchez-Ballester… - Molecules, 2021 - mdpi.com
The solid-state behaviour of two series of isomeric, phenol-substituted,
aminomethylphosphines, as the free ligands and bound to PtII, have been extensively …

PAEK-and PES-like perarylated phosphonium ionenes: Synthesis, thermal properties, and conductivity

SM Sims, H Brown, JR Hunter, RD Johnson… - Polymer, 2023 - Elsevier
Perarylated phosphonium salts are known to exhibit high degrees of thermal stability, often
in excess of 400° C. Here, the thermal and conductive properties of a series of perarylated …