Conspectus Chain-walking offers extensive opportunities for innovating synthetic methods
that involve constructing chemical bonds at unconventional sites. This approach provides …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

The direct difunctionalization of alkenes, a cheap and abundant feedstock, represents one of
the most attractive strategies for increasing molecular complexity in synthetic organic …

A highly regioselective Ni‐catalyzed electrochemical reductive relay cross‐coupling
between an aryl halide and an alkyl halide has been developed in an undivided cell …

In contrast to the extensive but non-recyclable use of tetraalkoxydiboron (4) compounds as
stoichiometric reagents in diverse reactions, this article reports an atom-economical reaction …

A NiH‐catalyzed migratory hydroalkylation of alkenyl amines with predictable and
switchable regioselectivity is reported. By utilizing a ligand‐controlled, directing group …

Remote functionalization of alkenes via chain walking has generally been limited to C (sp3)–
H bonds α and β to polar-functional units, while γ-C (sp3)–H functionalization through …

Migration of metals along a carbon chain is triggered by two of the most common
organometallic elementary steps–β-hydride (β-H) elimination and alkene hydrometallation …

Enantioselective difunctionalization of alkenes constitutes an efficient strategy to assemble
complex chiral molecules from simple racemic or achiral starting materials. Here we present …

Herein, we report the first Ni-catalyzed enantioselective deaminative alkylation of amino acid
and peptide derivatives with unactivated olefins. Key for success was the discovery of a new …