Sulfur (VI)‐fluoride exchange linkage as a next generation of click chemistry was introduced
by Sharpless and coworkers in 2014. Distinguished from CuAAC, the SuFEx reaction …

Abstract Sulfur (VI)‐fluoride exchange (SuFEx) chemistry, an all‐encompassing term for
substitution events that replace fluoride at an electrophilic sulfur (VI), enables the rapid and …

The carbonyl group forms an integral part of several drug molecules and materials; hence,
synthesis of carbonylated compounds remains an intriguing area of research for synthetic …

We report the discovery of a straightforward protocol to convert phenols into the
corresponding aryl triflates using 1‐methyl‐3‐((trifluoromethyl) sulfonyl)‐1, 3‐dihydro‐2H …

Abstract Sulfur (VI) Fluoride Exchange (SuFEx) chemistry stands as a well‐established
method for swiftly constructing complex molecules in a modular fashion. An especially …

Abstract Indan‐1, 3‐diones stand as versatile precursors to a plethora of complex molecules
with wide applications; however, their direct cross‐coupling methodologies remain largely …

A pressure gauge was incorporated into a two‐chamber glass H‐tube to continuously
monitor the pressure inside a reactor when working with gases. The ex situ generated H2 …

In a quest for efficient SuFEx-type transformations we studied reactions of amines with 4-
fluorobenzenesulfonyl fluoride. The substrate may react by fluoride substitution at the …

A practical and efficient Suzuki coupling of phenols has been developed by using trans-NiCl
(o-Tol)(PCy3) 2/2PCy3 as a catalyst in the presence of tosyl fluoride as an activator. The key …

Dipolar cycloadditions are the preferred method to generate five‐membered heterocyclic
rings. Surprisingly, cycloadditions based on acyl‐isocyanide ylides have remained …