Self-assembled stereomutation with supramolecular chirality inversion

G Liu, MG Humphrey, C Zhang, Y Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
Supramolecular chirality is involved not only in biological events such as gene
communication, replication, and enzyme catalysis but also in artificial self-assembly systems …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

Supramolecular chirality in self-assembled systems

M Liu, L Zhang, T Wang - Chemical reviews, 2015 - ACS Publications
Chirality is a basic characteristic of living matter and nature. During the evolution of life on
our planet, nature has favored one kind of chirality, thereby selecting the l-amino acids (with …

Chiral nanoarchitectonics: towards the design, self‐assembly, and function of nanoscale chiral twists and helices

L Zhang, T Wang, Z Shen, M Liu - Advanced Materials, 2016 - Wiley Online Library
Helical structures such as double helical DNA and the α‐helical proteins found in biological
systems are among the most beautiful natural structures. Chiral nanoarchitectonics, which is …

A novel supramolecular metallogel-based high-resolution anion sensor array

Q Lin, TT Lu, X Zhu, B Sun, QP Yang, TB Wei… - Chemical …, 2015 - pubs.rsc.org
A novel anion sensor array based on supramolecular metallogels has been developed. It
could accurately identify CN−, SCN−, S2− and I− in water. Interestingly, this sensor array is …

Distance matters: biasing mechanism, transfer of asymmetry, and stereomutation in N-annulated perylene bisimide supramolecular polymers

MA Martínez, A Doncel-Giménez, J Cerdá… - Journal of the …, 2021 - ACS Publications
The synthesis of two series of N-annulated perylene bisimides (PBIs), compounds 1 and 2,
is reported, and their self-assembling features are thoroughly investigated by a complete set …

[图书][B] Chiroptical spectroscopy: fundamentals and applications

PL Polavarapu - 2016 - taylorfrancis.com
This book details chiroptical spectroscopic methods: electronic circular dichroism (ECD),
optical rotatory dispersion (ORD), vibrational circular dichroism (VCD), and vibrational …

Hierarchy of asymmetry in chiral supramolecular polymers: toward functional, helical supramolecular structures

Y Dorca, EE Greciano, JS Valera… - … A European Journal, 2019 - Wiley Online Library
The formation of helical structures through the supramolecular polymerization of a variety of
self‐assembling units is reviewed. These scaffolds are usually obtained by efficient transfer …

The helix to super‐helix transition in the self‐assembly of π‐systems: superseding of molecular chirality at hierarchical level

M Hifsudheen, RK Mishra… - Angewandte …, 2017 - Wiley Online Library
Higher‐order super‐helical structures derived from biological molecules are known to
evolve through opposite coiling of the initial helical fibers, as seen in collagen protein. A …

A dynamic supramolecular polymer with stimuli-responsive handedness for in situ probing of enzymatic ATP hydrolysis

M Kumar, P Brocorens, C Tonnelé, D Beljonne… - Nature …, 2014 - nature.com
Abstract Design of artificial systems, which can respond to fluctuations in concentration of
adenosine phosphates (APs), can be useful in understanding various biological processes …