Protic ionic liquids in energy storage devices: Past, present and future perspective

T Stettner, A Balducci - Energy Storage Materials, 2021 - Elsevier
The development of new and especially safer electrolytes is an important task in the
development of modern electrochemical energy storage devices. One promising approach …

[HTML][HTML] Ionogels based on protic ionic liquid-lithium salt mixtures

JJ Parajó, P Vallet, M Villanueva, O Cabeza… - Journal of Molecular …, 2024 - Elsevier
The effect of the addition of lithium nitrate on the liquid range and electrical conductivity of
mixtures of a protic ionic liquid, ethylammonium nitrate (EAN) with LiNO 3 is reported in this …

[HTML][HTML] Anomalous behaviour of the ionic conductivity of nanoconfined IL-lithium salt mixtures

P Vallet, JJ Parajó, A Santiago-Alonso… - Journal of Molecular …, 2024 - Elsevier
The effect of salt addition on the protic ionic liquid (IL) ethylimidazolium nitrate is analysed in
this work in terms of structural changes measured by NMR, thermal behaviour and ionic …

Enthalpy of solvation of alkali metal salts in a protic ionic liquid: Effect of cation charge and size

JJ Parajo, JM Otero-Mato, AIMCL Ferreira… - Journal of Molecular …, 2022 - Elsevier
An experimental and theoretical study of solution and solvation of mono-and divalent alkali
metal cations in the protic ionic liquid (IL) ethylammonium nitrate (EAN) is reported. High …

[HTML][HTML] Unusual ion transport behaviour of ethylammonium nitrate mixed with lithium nitrate

A Filippov, AS Alexandrov, R Gimatdinov… - Journal of Molecular …, 2021 - Elsevier
The diffusivity of ions and ionic conductivity of ethylammonium nitrate (EAN) mixed with
lithium nitrate (LiNO 3) has been carried out as a function of Li-salt concentration and …

Synthesis, microstructure and volumetry of novel metal thiocyanate ionic liquids with [BMIM] cation

O Cabeza, LM Varela, E Rilo, L Segade… - Journal of Molecular …, 2019 - Elsevier
We present a new family of ionic liquids (ILs) with a common cation, 1-butyl-3-methyl
imidazolium, the popular [BMIM]+(also written C 4 C 1 Im+) and a variety of anionic …

Evolution of Water State in the “Ionic Liquid EAN/Al(NO3)3/H2O” System Depending on Temperature and Aluminum Salt Concentration

M Ubovich, KA Mukhin… - The Journal of …, 2024 - ACS Publications
Although lithium salts are the most successful materials for electrochemical devices so far,
there is growing interest in electrolytes containing divalent and trivalent salts, which are …

The State of Water in “Ionic Liquid [bmim]Cl/AlCl3/H2O” Systems

M Ubovich, VV Matveev, MA Vovk… - The Journal of Physical …, 2023 - ACS Publications
The unique physical and chemical properties of ionic liquids (ILs) determine their numerous
applications in “green” chemistry and material science. Recently, systems based on ILs have …

Thermal Characterization of [C2Im][NO3] and Multivalent Nitrate Salts Mixtures

P Vallet, JJ Parajó, A Santiago-Alonso, M Villanueva… - Crystals, 2024 - mdpi.com
Due to their intrinsic properties, the current applicability of ionic liquids is enormous. In
particular, their use in electrochemistry is beyond question. Numerous studies on these …

Al3+ solvation in solutions of aluminum nitrate in a protic ionic liquid: Nuclear magnetic resonance verification of the solvation shell composition

VV Matveev, A Ievlev, M Šoltésová… - Magnetic …, 2022 - Wiley Online Library
The closest environment of Al3+ cations was analyzed in detail in solutions of aluminum
nitrate in the prototypical protic ionic liquid ethyl ammonium nitrate (EAN) using 1H and 14N …