Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

A Nakada, T Matsumoto, HC Chang - Coordination Chemistry Reviews, 2022 - Elsevier
A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …

Gas-phase femtosecond particle spectroscopy: a bottom-up approach to nucleotide dynamics

VG Stavros, JRR Verlet - Annual Review of Physical Chemistry, 2016 - annualreviews.org
We summarize how gas-phase ultrafast charged-particle spectroscopy has been used to
provide an understanding of the photophysics of DNA building blocks. We focus on adenine …

Different timescales during ultrafast stilbene isomerization in the gas and liquid phases revealed using time-resolved photoelectron spectroscopy

C Wang, MDJ Waters, P Zhang, J Suchan… - Nature …, 2022 - nature.com
Directly contrasting ultrafast excited-state dynamics in the gas and liquid phases is crucial to
understanding the influence of complex environments. Previous studies have often relied on …

Solvent-dependent structural dynamics in the ultrafast photodissociation reaction of triiodide observed with time-resolved x-ray solution scattering

A Nimmrich, MR Panman, O Berntsson… - Journal of the …, 2023 - ACS Publications
Resolving the structural dynamics of bond breaking, bond formation, and solvation is
required for a deeper understanding of solution-phase chemical reactions. In this work, we …

The role of πσ* states in the photochemistry of heteroaromatic biomolecules and their subunits: insights from gas-phase femtosecond spectroscopy

GM Roberts, VG Stavros - Chemical Science, 2014 - pubs.rsc.org
In an effort to illuminate why nature has chosen a particular set of bio-molecular 'building-
blocks' for life, recent years have seen an up-surge of gas-phase spectroscopy experiments …

Probing the ultrafast energy dissipation mechanism of the sunscreen oxybenzone after UVA irradiation

LA Baker, MD Horbury, SE Greenough… - The journal of …, 2015 - ACS Publications
Oxybenzone is a common constituent of many commercially available sunscreens providing
photoprotection from ultraviolet light incident on the skin. Femtosecond transient electronic …

Photodissociation dynamics of phenol: Multistate trajectory simulations including tunneling

X Xu, J Zheng, KR Yang, DG Truhlar - Journal of the American …, 2014 - ACS Publications
We report multistate trajectory simulations, including coherence, decoherence, and
multidimensional tunneling, of phenol photodissociation dynamics. The calculations are …

On the participation of photoinduced N–H bond fission in aqueous adenine at 266 and 220 nm: a combined ultrafast transient electronic and vibrational absorption …

GM Roberts, HJB Marroux, MP Grubb… - The Journal of …, 2014 - ACS Publications
A combination of ultrafast transient electronic absorption spectroscopy (TEAS) and transient
vibrational absorption spectroscopy (TVAS) is used to investigate whether photoinduced N …

A perspective on the ultrafast photochemistry of solution-phase sunscreen molecules

LA Baker, SE Greenough… - The Journal of Physical …, 2016 - ACS Publications
Sunscreens are one of the most common ways of providing on-demand additional
photoprotection to the skin. Ultrafast transient absorption spectroscopy has recently proven …

Ultrafast photo-induced ligand solvolysis of cis-[Ru (bipyridine) 2 (nicotinamide) 2] 2+: experimental and theoretical insight into its photoactivation mechanism

SE Greenough, GM Roberts, NA Smith… - Physical Chemistry …, 2014 - pubs.rsc.org
Mechanistic insight into the photo-induced solvent substitution reaction of cis-[Ru
(bipyridine) 2 (nicotinamide) 2] 2+(1) is presented. Complex 1 is a photoactive species …