Photobiocatalytic strategies for organic synthesis

MA Emmanuel, SG Bender, C Bilodeau… - Chemical …, 2023 - ACS Publications
Biocatalysis has revolutionized chemical synthesis, providing sustainable methods for
preparing various organic molecules. In enzyme-mediated organic synthesis, most reactions …

Artificial photosynthesis systems for solar energy conversion and storage: platforms and their realities

Z Wang, Y Hu, S Zhang, Y Sun - Chemical Society Reviews, 2022 - pubs.rsc.org
In natural photosynthesis, photosynthetic organisms such as green plants realize efficient
solar energy conversion and storage by integrating photosynthetic components on the …

Photo-biocatalysis: biotransformations in the presence of light

L Schmermund, V Jurkas, FF Özgen, GD Barone… - Acs …, 2019 - ACS Publications
Light has received increased attention for various chemical reactions but also in
combination with biocatalytic reactions. Because currently only a few enzymatic reactions …

Semi-biological approaches to solar-to-chemical conversion

X Fang, S Kalathil, E Reisner - Chemical Society Reviews, 2020 - pubs.rsc.org
This review presents a comprehensive summary of the recent development in semi-artificial
photosynthesis, a biological-material hybrid approach to solar-to-chemical conversion that …

Photobiocatalysis: activating redox enzymes by direct or indirect transfer of photoinduced electrons

SH Lee, DS Choi, SK Kuk… - Angewandte Chemie …, 2018 - Wiley Online Library
Biocatalytic transformation has received increasing attention in the green synthesis of
chemicals because of the diversity of enzymes, their high catalytic activities and specificities …

Photoenzymatic conversion of enamides to enantioenriched benzylic amines enabled by visible-light-induced single-electron reduction

J Zhang, Q Zhang, B Chen, J Yu, B Wang… - ACS Catalysis, 2023 - ACS Publications
The enantioselective reduction of enamides is an efficient and atom-economical way to
construct chiral amine motifs. In contrast to transition-metal complex based asymmetric …

Discovery, characterization, engineering, and applications of ene-reductases for industrial biocatalysis

HS Toogood, NS Scrutton - ACS catalysis, 2018 - ACS Publications
Recent studies of multiple enzyme families collectively called ene-reductases (ERs) have
highlighted potential industrial applications of these biocatalysts in the production of fine and …

Biocatalytic reduction reactions from a chemist's perspective

F Hollmann, DJ Opperman… - Angewandte Chemie …, 2021 - Wiley Online Library
Reductions play a key role in organic synthesis, producing chiral products with new
functionalities. Enzymes can catalyse such reactions with exquisite stereo‐, regio‐and …

Carbon dots as versatile photosensitizers for solar-driven catalysis with redox enzymes

GAM Hutton, B Reuillard, BCM Martindale… - Journal of the …, 2016 - ACS Publications
Light-driven enzymatic catalysis is enabled by the productive coupling of a protein to a
photosensitizer. Photosensitizers used in such hybrid systems are typically costly, toxic …

Photo‐biocatalytic cascades: combining chemical and enzymatic transformations fueled by light

FF Özgen, ME Runda, S Schmidt - ChemBioChem, 2021 - Wiley Online Library
In the field of green chemistry, light–an attractive natural agent–has received particular
attention for driving biocatalytic reactions. Moreover, the implementation of light to drive …