Advances of atomically dispersed catalysts from single-atom to clusters in energy storage and conversion applications

Y Wang, X Cui, J Zhang, J Qiao, H Huang, J Shi… - Progress in Materials …, 2022 - Elsevier
Owing to the special structural characteristics and maximized efficiency, atomically
dispersed catalysts (ADCs) with different atom sizes ranged from the single atom to clusters …

Metal supported graphene catalysis: A review on the benefits of nanoparticular supported specialty sp2 carbon catalysts on enhancing the activities of multiple …

MB Burkholder, FBA Rahman, EH Chandler Jr… - Carbon Trends, 2022 - Elsevier
Transition metal-based heterogeneous catalysts are widely used across many industries.
The prevalence of these materials across so many domains has inspired research into many …

Anchoring positively charged Pd single atoms in ordered porous ceria to boost catalytic activity and stability in Suzuki coupling reactions

X Tao, R Long, D Wu, Y Hu, G Qiu, Z Qi, B Li, R Jiang… - Small, 2020 - Wiley Online Library
Single‐atom (SA) catalysis bridging homogeneous and heterogeneous catalysis offers new
opportunities for organic synthesis, but developing SA catalysts with high activity and …

Oxygen-doped carbon supports modulate the hydrogenation activity of palladium nanoparticles through electronic metal–support interactions

RG Rao, R Blume, MT Greiner, P Liu, TW Hansen… - ACS …, 2022 - ACS Publications
In heterogeneous catalysis, synergies between the metal active phase and oxide support
can enhance the catalytic activity through electronic metal–support interactions (EMSI). Such …

A Co–Cu bimetallic magnetic nanocatalyst with synergistic and bifunctional performance for the base-free Suzuki, Sonogashira, and C–N cross-coupling reactions in …

MA Nasseri, Z Rezazadeh, M Kazemnejadi… - Dalton …, 2020 - pubs.rsc.org
A novel magnetically recyclable bimetallic catalyst was prepared by anchoring imidazolium
moiety and PEG chains on Fe3O4 NPs and named as Fe3O4@ PEG/Cu–Co. It was found to …

Heterogeneous catalysis by ultra-small bimetallic nanoparticles surpassing homogeneous catalysis for carbon–carbon bond forming reactions

N Norouzi, MK Das, AJ Richard, AA Ibrahim… - Nanoscale, 2020 - pubs.rsc.org
Palladium catalyzed cross-coupling reactions represent a significant advancement in
contemporary organic synthesis as these reactions are of strategic importance in the area of …

Experimental and computational study of the catalytic activity of Pd and PdCu nanoparticle catalysts and clusters supported on reduced graphene oxide and graphene …

T Sengupta, M Moody, M Das, AC Reber… - Applied Catalysis A …, 2023 - Elsevier
The catalytic activity of Pd and PdCu nanoparticle catalysts and clusters supported on
reduced graphene oxide (RGO) and graphene acid (GA) toward the Suzuki cross-coupling …

Carbon‐Based Material‐Supported Palladium Nanocatalysts in Coupling Reactions: Discussion on their Stability and Heterogeneity

M Zhao, Y Wu, JP Cao - Applied Organometallic Chemistry, 2020 - Wiley Online Library
Scientific interest in carbon‐based materials (CBMs) has grown dramatically over the past
few decades. Due to a variety of atomic orbital hybrid forms (sp, sp2 and sp3 hybridization) …

Graphitic Carbon Nitride (g‐C3N4) Supported Palladium Species: An Efficient Heterogeneous Photocatalyst Surpassing Homogeneous Thermal Heating Systems …

N Wang, L Ma, J Wang, Y Zhang, R Jiang - ChemPlusChem, 2019 - Wiley Online Library
Suzuki coupling is of paramount importance in C− C coupling reactions. However, Suzuki
coupling reactions are generally catalyzed by homogeneous catalysts under thermal …

Transforming redox properties of clusters using phosphine ligands

AC Reber, D Bista, V Chauhan… - The Journal of Physical …, 2019 - ACS Publications
Organic ligands that protect the surfaces of clusters and nanoparticles against reactions and
control the rate of growth are generally considered to be inert passive coatings. Here, we …