Light olefin synthesis from a diversity of renewable and fossil feedstocks: state-of the-art and outlook
SA Chernyak, M Corda, JP Dath… - Chemical Society …, 2022 - pubs.rsc.org
Light olefins are important feedstocks and platform molecules for the chemical industry.
Their synthesis has been a research priority in both academia and industry. There are many …
Their synthesis has been a research priority in both academia and industry. There are many …
Heterogeneous alkane dehydrogenation catalysts investigated via a surface organometallic chemistry approach
The selective conversion of light alkanes (C2–C6 saturated hydrocarbons) to the
corresponding alkene is an appealing strategy for the petrochemical industry in view of the …
corresponding alkene is an appealing strategy for the petrochemical industry in view of the …
Design strategies of stable catalysts for propane dehydrogenation to propylene
ML Sun, ZP Hu, HY Wang, YJ Suo, ZY Yuan - ACS Catalysis, 2023 - ACS Publications
Propylene is one of the most important building blocks for the chemical industry. Traditional
propylene production, which is based on oil-based cracking processes, is being challenged …
propylene production, which is based on oil-based cracking processes, is being challenged …
Single Co Sites in Ordered SiO2 Channels for Boosting Nonoxidative Propane Dehydrogenation
Searching for low-cost, environmentally friendly, and highly active catalysts for C–H bond
activation in propane dehydrogenation (PDH) reaction remains a great challenge. Herein …
activation in propane dehydrogenation (PDH) reaction remains a great challenge. Herein …
Coke deposition on Pt-based catalysts in propane direct dehydrogenation: Kinetics, suppression, and elimination
Pt-based catalysts are widely used in propane dehydrogenation to meet the dramatically
increased demand of propylene from an on-purpose catalytic process. Although the process …
increased demand of propylene from an on-purpose catalytic process. Although the process …
Highly active and selective sites for propane dehydrogenation in zeolite Ga-BEA
A highly selective Ga-modified zeolite BEA for propane dehydrogenation has been
synthesized by grafting Ga on Zn-BEA followed by removal of Zn in the presence of H2. A …
synthesized by grafting Ga on Zn-BEA followed by removal of Zn in the presence of H2. A …
Nature of GaOx Shells Grown on Silica by Atomic Layer Deposition
Gallia-based shells with a thickness varying from a submonolayer to ca. 2.5 nm were
prepared by atomic layer deposition (ALD) using trimethylgallium, ozone, and partially …
prepared by atomic layer deposition (ALD) using trimethylgallium, ozone, and partially …
Steering the reaction pathway of syngas-to-light olefins with coordination unsaturated sites of ZnGaOx spinel
Significant progress has been demonstrated in the development of bifunctional oxide-zeolite
catalyst concept to tackle the selectivity challenge in syngas chemistry. Despite general …
catalyst concept to tackle the selectivity challenge in syngas chemistry. Despite general …
Metastable gallium hydride mediates propane dehydrogenation on H2 co-feeding
In heterogeneous catalysis, the catalytic dehydrogenation reactions of hydrocarbons often
exhibit a negative pressure dependence on hydrogen due to the competitive chemisorption …
exhibit a negative pressure dependence on hydrogen due to the competitive chemisorption …
Structure and Role of a Ga-Promoter in Ni-Based Catalysts for the Selective Hydrogenation of CO2 to Methanol
Supported, bimetallic catalysts have shown great promise for the selective hydrogenation of
CO2 to methanol. In this study, we decipher the catalytically active structure of Ni–Ga-based …
CO2 to methanol. In this study, we decipher the catalytically active structure of Ni–Ga-based …