Thiolactone chemistry, a versatile platform for macromolecular engineering

N Illy, E Mongkhoun - Polymer Chemistry, 2022 - pubs.rsc.org
Thiolactones are often described as latent thiols. They can be ring-opened by hydroxy or
amine groups releasing thiols, which can further react with a large variety of functional …

Protected thiol strategies in macromolecular design

F Goethals, D Frank, F Du Prez - Progress in Polymer Science, 2017 - Elsevier
Reactions involving thiols have been extensively applied in numerous polymeric systems
thanks to the reactive nature of the mercapto group, causing these reactions to be efficient …

Hydrogen‐Bonded Supramolecular Polymer Adhesives: Straightforward Synthesis and Strong Substrate Interaction

S Chen, Z Li, Y Wu, N Mahmood… - Angewandte Chemie …, 2022 - Wiley Online Library
High‐performance adhesives are of great interest in view of industrial demand. We herein
identify a straightforward synthetic strategy towards universal hydrogen‐bonded (H‐bonded) …

Coding and decoding libraries of sequence-defined functional copolymers synthesized via photoligation

N Zydziak, W Konrad, F Feist, S Afonin… - Nature …, 2016 - nature.com
Designing artificial macromolecules with absolute sequence order represents a
considerable challenge. Here we report an advanced light-induced avenue to …

Thioester functional polymers

S Aksakal, R Aksakal, CR Becer - Sulfur‐Containing Polymers …, 2021 - Wiley Online Library
Inspired by the abundance and versatility of thioester in nature, much attention has been
paid to thioester functionalized materials, allowing applications that range from responsive …

RAFT-mediated, visible light-initiated single unit monomer insertion and its application in the synthesis of sequence-defined polymers

C Fu, Z Huang, CJ Hawker, G Moad, J Xu… - Polymer Chemistry, 2017 - pubs.rsc.org
In this communication, we report a catalyst-free methodology for single unit monomer
insertion (SUMI) into reversible addition–fragmentation chain transfer (RAFT) agents …

Synthesis and Thermoresponsive Behaviors of Thermo-, pH-, CO2-, and Oxidation-Responsive Linear and Cyclic Graft Copolymers

H Zhang, W Wu, X Zhao, Y Zhao - Macromolecules, 2017 - ACS Publications
Rational macromolecular design allows us to construct multiresponsive architectural
polymers with a potential toward multipurpose applications. This study aims at synthesis and …

Synthesis of multifunctional homopolymers via sequential post-polymerization reactions

T Kubo, CP Easterling, RA Olson, BS Sumerlin - Polymer Chemistry, 2018 - pubs.rsc.org
Multifunctional homopolymers, homopolymers with multiple pendent functionalities, can offer
unparalleled properties not possible with traditional polymers. Preparation of multifunctional …

Multifunctional homopolymers: postpolymerization modification via sequential nucleophilic aromatic substitution

T Kubo, CA Figg, JL Swartz, WLA Brooks… - …, 2016 - ACS Publications
Despite recent progress for efficient and precise synthesis of functional polymers, few
reports describe postpolymerization functionalization strategies for the controlled …

Polythiolactone‐Decorated Silica Particles: A Versatile Approach for Surface Functionalization, Catalysis and Encapsulation

DW Kurka, M Niehues, S Kudruk… - … A European Journal, 2021 - Wiley Online Library
The surface chemistry of colloidal silica has tremendous effects on its properties and
applications. Commonly the design of silica particles is based on their de novo synthesis …