Recent advances in catalytic asymmetric construction of atropisomers
JK Cheng, SH Xiang, S Li, L Ye, B Tan - Chemical Reviews, 2021 - ACS Publications
Atropisomerism is a stereochemical behavior portrayed by three-dimensional molecules that
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …
bear rotationally restricted σ bond. Akin to the well-represented point-chiral molecules …
Oxidative C–H/C–H coupling reactions between two (hetero) arenes
Y Yang, J Lan, J You - Chemical reviews, 2017 - ACS Publications
Transition metal-mediated C–H bond activation and functionalization represent one of the
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …
most straightforward and powerful tools in modern organic synthetic chemistry. Bi (hetero) …
Synthetic applications of oxidative aromatic coupling—from biphenols to nanographenes
M Grzybowski, B Sadowski… - Angewandte Chemie …, 2020 - Wiley Online Library
Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …
aromatic compounds. It is a method of choice for the assembly of large and bewildering …
Aerobic copper-catalyzed organic reactions
SE Allen, RR Walvoord, R Padilla-Salinas… - Chemical …, 2013 - ACS Publications
The chemistry of copper is extremely rich because it can easily access Cu0, CuI, CuII, and
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
CuIII oxidation states allowing it to act through one-electron or two-electron processes. As a …
Rhodium-catalyzed atroposelective oxidative C–H/C–H cross-coupling reaction of 1-aryl isoquinoline derivatives with electron-rich heteroarenes
Rhodium (III)-catalyzed enantioselective oxidative C–H/C–H cross-coupling reaction
between two arenes is disclosed. With the combination of a chiral CpRh (III) complex and a …
between two arenes is disclosed. With the combination of a chiral CpRh (III) complex and a …
Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2 Model Systems to Organometallic Transformations
R Trammell, K Rajabimoghadam… - Chemical …, 2019 - ACS Publications
Copper is one of the most abundant and less toxic transition metals. Nature takes advantage
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …
of the bioavailability and rich redox chemistry of Cu to carry out oxygenase and oxidase …
Enantioselective Ni-catalyzed electrochemical synthesis of biaryl atropisomers
H Qiu, B Shuai, YZ Wang, D Liu, YG Chen… - Journal of the …, 2020 - ACS Publications
A scalable enantioselective nickel-catalyzed electrochemical reductive homocoupling of aryl
bromides has been developed, affording enantioenriched axially chiral biaryls in good yield …
bromides has been developed, affording enantioenriched axially chiral biaryls in good yield …
Comparison of oxidative aromatic coupling and the Scholl reaction
M Grzybowski, K Skonieczny… - Angewandte Chemie …, 2013 - Wiley Online Library
Does the dehydrogenative coupling of aromatic compounds mediated by AlCl3 at high
temperatures and also by FeCl3, MoCl5, PIFA, or K3 [Fe (CN) 6] at room temperature …
temperatures and also by FeCl3, MoCl5, PIFA, or K3 [Fe (CN) 6] at room temperature …
Copper‐Catalyzed Aerobic Oxidative C H Functionalizations: Trends and Mechanistic Insights
AE Wendlandt, AM Suess… - Angewandte Chemie …, 2011 - Wiley Online Library
The selective oxidation of C H bonds and the use of O2 as a stoichiometric oxidant
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …
represent two prominent challenges in organic chemistry. Copper (II) is a versatile oxidant …
Direct C− H transformation via iron catalysis
CL Sun, BJ Li, ZJ Shi - Chemical Reviews, 2011 - ACS Publications
The development and application of efficient, convenient, selective, and environmentally
benign synthetic methods is highly desirable in organic chemistry. With this requirement …
benign synthetic methods is highly desirable in organic chemistry. With this requirement …