Radical-involved transition metal (TM) catalysis has greatly enabled new reactivities in
recent decades. Copper-catalyzed radical relay offers enormous potential in C (sp3)–H …

The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

The arylethylamine pharmacophore is conserved across a range of biologically active
natural products and pharmaceuticals, particularly in molecules that act on the central …

The construction of carbon–heteroatom bonds is one of the most active areas of research in
organic chemistry because the function of organic molecules is often derived from the …

Chiral boronic esters are a class of versatile building blocks. We describe herein an
asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl …

A novel asymmetric radical strategy for the straightforward synthesis of atropisomerically
chiral vinyl arenes has been established herein, proceeding through copper-catalyzed …

Radical‐involved multicomponent difunctionalization of 1, 3‐dienes has recently emerged
as a promising strategy for rapid synthesis of valuable allylic compounds in one‐pot …

Azidation of alkenes is an efficient protocol to synthesize organic azides which are important
structural motifs in organic synthesis. Enantioselective radical azidation, as a useful strategy …

Catalytic asymmetric cyanation is a straightforward route to α-chiral nitriles that has
previously relied on the enantioselective attack of cyanide on unsaturated electrophiles or …

The copper-catalyzed enantioselective intermolecular radical 1, 2-carboamination of
alkenes with readily accessible alkyl halides is an appealing strategy for producing chiral …