C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

Until recently, computational tools were mainly used to explain chemical reactions after
experimental results were obtained. With the rapid development of software and hardware …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

Conspectus Metal carbene plays a vital role in modern organic synthesis. The neutral
divalent carbon of metal carbene renders it an active intermediate throughout a range of …

Abstract para‐Selective C− H borylation of benzamides and pyridines has been achieved by
cooperative iridium/aluminum catalysis. A combination of iridium catalysts commonly …

C–H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …

The development of an efficient method for the site‐selective substitution of unprotected
phenols has long been considered as an attractive but challenging task. Herein, we …

Asymmetric insertion of an arylvinylcarbenoid into the C–H bond for direct enantioselective
C (sp2)-H functionalization of aniline derivatives catalyzed by a rhodium (I)-diene complex …

Reported herein is the unprecedented gold‐catalyzed formal [4+ 1]/[4+ 3] cycloadditions of
diazo esters with hexahydro‐1, 3, 4‐triazines, thus providing five‐and seven‐membered …

We report asymmetric dearomatization of phenols using Ag carbenoids from α-
diazoacetamides. The Ag catalyst promoted intramolecular dearomatization of phenols …